中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Fluorodiphenylethene-Containing Donor-Acceptor Conjugated Copolymers with Noncovalent Conformational Locks for Efficient Polymer Field-Effect Transistors

文献类型:期刊论文

作者Zhang, Weifeng; Shi, Keli; Huang, Jianyao; Gao, Dong; Mao, Zupan; Li, Dizao; Yu, Gui
刊名MACROMOLECULES
出版日期2016-04-12
卷号49期号:7页码:2582-2591
英文摘要The diphenylethene moiety is a versatile building block that offers several chemically functionalizable sites, allowing easy modulation of electronic properties of the resulting polymers and providing numerous opportunities for discovering related structure property relationships. In this study, we report a series of difluorodiphenylethene-based copolymers with noncovalent conformational locks for applications in polymer field-effect transistors. Different fluorination positions lead to different type of intra- and intermolecular interactions, backbone conformations, and eventually different device performances. 2,2'-Difluorodiphenylethene-based copolymers P2DFPE-n containing F H C conformation locks exhibit obviously enhanced hole mobilities of 1.3-1.5 cm(2) V-1 s(-1), whereas 3,3'-difluorodiphenylethenebased copolymers P3DFPE-n containing F center dot center dot center dot H-C and F center dot center dot center dot S conformation locks show lower mobilities of 0.2-0.4 cm(2) V-1 s(-1). AFM and 2D-GRXD investigations indicate that P2DFPE-n takes predominantly edge-on orientation packing mode, forming crystalline and highly ordered thin films with small pi-pi stacking distances of 3.59-3.68 angstrom. However, P3DFPE-n adopts random close molecular packing mode in solid states.
收录类别SCI
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/36027]  
专题化学研究所_有机固体实验室
作者单位Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Weifeng,Shi, Keli,Huang, Jianyao,et al. Fluorodiphenylethene-Containing Donor-Acceptor Conjugated Copolymers with Noncovalent Conformational Locks for Efficient Polymer Field-Effect Transistors[J]. MACROMOLECULES,2016,49(7):2582-2591.
APA Zhang, Weifeng.,Shi, Keli.,Huang, Jianyao.,Gao, Dong.,Mao, Zupan.,...&Yu, Gui.(2016).Fluorodiphenylethene-Containing Donor-Acceptor Conjugated Copolymers with Noncovalent Conformational Locks for Efficient Polymer Field-Effect Transistors.MACROMOLECULES,49(7),2582-2591.
MLA Zhang, Weifeng,et al."Fluorodiphenylethene-Containing Donor-Acceptor Conjugated Copolymers with Noncovalent Conformational Locks for Efficient Polymer Field-Effect Transistors".MACROMOLECULES 49.7(2016):2582-2591.

入库方式: OAI收割

来源:化学研究所

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