Aggregates-Based Boronlectins with Pyrene as Fluorophore: Multichannel Discriminative Sensing of Monosaccharides and Their Applications
文献类型：期刊论文
| 作者 | Zhang, Xiao-tai1; Wang, Shu2; Xing, Guo-wen1 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2016-05-18 |
| 卷号 | 8期号:19页码:12007-12017 |
| 关键词 | boronlectin pyrene monosaccharide aggregates sensor |
| 英文摘要 | Four-channel. fluorescence assay toward six monosaccharides was achieved by employing two novel pyrene-functionalized boronlectins with flexible diboronic acid as receptors. The effects of pH values and aging time on the sensor properties, were thoroughly evaluated by UV-vis, fluorescence spectroscopy and dynamic light scattering. We find. that the fluorescence relative ratios were highly correlated with analyte concentrations at mu M level. The flexibility of the receptors was perceived as an indispensable factor to produce diverse fluorescence signals toward different monosaccharides. Most importantly, integration of four fluorescence channels derived from the two sensors enables an excellent discrimination for all tested monosaccharides at a certain concentration or a concentration range via linear discriminant analysis (LDA). It is proposed that the multiple flexible linkers in the boronlectins could increase their self-adaptive capacity for different analytes, and facilitate the formation of stable boronlectin-sugar aggregate assemblies; In addition, practical sensing,of glucose in the simulative blood and urine was illustrated. to be feasible in the presence of interferences at physiological concentrations. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/36141]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China 2.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xiao-tai,Wang, Shu,Xing, Guo-wen. Aggregates-Based Boronlectins with Pyrene as Fluorophore: Multichannel Discriminative Sensing of Monosaccharides and Their Applications[J]. ACS APPLIED MATERIALS & INTERFACES,2016,8(19):12007-12017. |
| APA | Zhang, Xiao-tai,Wang, Shu,&Xing, Guo-wen.(2016).Aggregates-Based Boronlectins with Pyrene as Fluorophore: Multichannel Discriminative Sensing of Monosaccharides and Their Applications.ACS APPLIED MATERIALS & INTERFACES,8(19),12007-12017. |
| MLA | Zhang, Xiao-tai,et al."Aggregates-Based Boronlectins with Pyrene as Fluorophore: Multichannel Discriminative Sensing of Monosaccharides and Their Applications".ACS APPLIED MATERIALS & INTERFACES 8.19(2016):12007-12017. |
入库方式： OAI收割
来源：化学研究所
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