New polymethylene-based AB(2) star copolymers synthesized via a combination of polyhomologation of ylides and atom transfer radical polymerization
文献类型：期刊论文
| 作者 | Xue Y(薛杨)1; Zhang SS(张双双)1; Cui K(崔崑)1; Huang J(黄晋)1; Zhao QL(赵巧玲)1; Lan P(蓝平)1; Cao SK(曹少魁)1; Ma Z(马志)1 |
| 刊名 | RSC Adv.
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:10页码:7090-7097 |
| 其他题名 | 叶立德同源聚合与ATRP聚合相结合制备新型聚亚甲基AB2星形共聚物 |
| 通讯作者 | 马志 |
| 英文摘要 | New polymethylene-based AB(2) star polymers with well-defined architecture and various components were synthesized using a combination of polyhomologation of ylides and atomic transfer radical polymerization (ATRP). The chain structures of polymethylene-b-(polystyrene)(2) (PM-b-(PS)(2)) and polymethylene-b-( poly(methyl methacrylate))(2) (PM-b-(PMMA)(2)) were characterized through H-1 NMR, GPC and FT-IR. The porous films of such star copolymers were fabricated via a static breath-figure (BF) process. The influence of polymer molecular weight, solution concentration and environmental temperature on the morphology of such block copolymer films was investigated. The porous surface of such a film presents hydrophobic behaviour with a static water-droplet contact angle of ca. 108 degrees. The electrospinning of PM-b-(PS)(2) was performed using CHCl3 as a solvent and the wrinkle-like polymer particles with nanopores on their surface were obtained. |
| 学科主题 | 高分子化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/c4ra14504f |
| 语种 | 英语 |
| WOS记录号 | WOS:000347609400010 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39830]  |
| 专题 | 上海有机化学研究所_高分子材料研究室 |
| 作者单位 | 1.中科院上海有机化学研究所, 有机功能分子合成与组装化学重点实验室 2.郑州大学 3.嘉兴学院 |
| 推荐引用方式 GB/T 7714 | Xue Y,Zhang SS,Cui K,et al. New polymethylene-based AB(2) star copolymers synthesized via a combination of polyhomologation of ylides and atom transfer radical polymerization[J]. RSC Adv.,2015,5(10):7090-7097. |
| APA | 薛杨.,张双双.,崔崑.,黄晋.,赵巧玲.,...&马志.(2015).New polymethylene-based AB(2) star copolymers synthesized via a combination of polyhomologation of ylides and atom transfer radical polymerization.RSC Adv.,5(10),7090-7097. |
| MLA | 薛杨,et al."New polymethylene-based AB(2) star copolymers synthesized via a combination of polyhomologation of ylides and atom transfer radical polymerization".RSC Adv. 5.10(2015):7090-7097. |
入库方式： OAI收割
来源：上海有机化学研究所
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