Polyisobutylene-b-Poly(N,N-diethylacrylamide) Well-Defined Amphiphilic Diblock Copolymer: Synthesis and Thermo-Responsive Phase Behavior
文献类型：期刊论文
| 作者 | Ren CH(任春虹)1; Liu XW(刘训伟)1; Jiang X(江雪)1; Sun G(孙钢)1; Huang XY(黄晓宇)1 |
| 刊名 | J. Polym. Sci. Pol. Chem.
 |
| 出版日期 | 2015 |
| 卷号 | 53期号:9页码:1143-1150 |
| 其他题名 | Polyisobutylene-b-Poly(N,N-diethylacrylamide) Well-Defined Amphiphilic Diblock Copolymer: Synthesis and Thermo-Responsive Phase Behavior |
| 通讯作者 | 孙钢 ; 黄晓宇 |
| 英文摘要 | Polyisobutylene-b-poly(N,N-diethylacrylamide) (PIB-b-PDEAAm) well-defined amphiphilic diblock copolymers were synthesized by sequential living carbocationic polymerization and reversible addition-fragmentation chain transfer (RAFT) polymerization. The hydrophobic polyisobutylene segment was first built by living carbocationic polymerization of isobutylene at -70 degrees C followed by multistep transformations to give a well-defined (M-w/M-n=1.22) macromolecular chain transfer agent, PIB-CTA. The hydrophilic poly(N,N-diethylacrylamide) block was constructed by PIB-CTA mediated RAFT polymerization of N,N-diethylacrylamide at 60 degrees C to afford the desired well-defined PIB-b-PDEAAm diblock copolymers with narrow molecular weight distributions (M-w/M-n 1.26). Fluorescence spectroscopy, transmission electron microscope, and dynamic light scattering (DLS) were employed to investigate the self-assembly behavior of PIB-b-PDEAAm amphiphilic diblock copolymers in aqueous media. These diblock copolymers also exhibited thermo-responsive phase behavior, which was confirmed by UV-Vis and DLS measurements. (c) 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 1143-1150 |
| 学科主题 | 高分子化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/pola.27545 |
| 语种 | 英语 |
| WOS记录号 | WOS:000351634500010 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39838]  |
| 专题 | 上海有机化学研究所_高分子材料研究室 |
| 作者单位 | 1.中科院上海有机化学研究所, 有机功能分子合成与组装化学重点实验室 2.中国人民解放军济南军区总医院 |
| 推荐引用方式 GB/T 7714 | Ren CH,Liu XW,Jiang X,et al. Polyisobutylene-b-Poly(N,N-diethylacrylamide) Well-Defined Amphiphilic Diblock Copolymer: Synthesis and Thermo-Responsive Phase Behavior[J]. J. Polym. Sci. Pol. Chem.,2015,53(9):1143-1150. |
| APA | 任春虹,刘训伟,江雪,孙钢,&黄晓宇.(2015).Polyisobutylene-b-Poly(N,N-diethylacrylamide) Well-Defined Amphiphilic Diblock Copolymer: Synthesis and Thermo-Responsive Phase Behavior.J. Polym. Sci. Pol. Chem.,53(9),1143-1150. |
| MLA | 任春虹,et al."Polyisobutylene-b-Poly(N,N-diethylacrylamide) Well-Defined Amphiphilic Diblock Copolymer: Synthesis and Thermo-Responsive Phase Behavior".J. Polym. Sci. Pol. Chem. 53.9(2015):1143-1150. |
入库方式： OAI收割
来源：上海有机化学研究所
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