Zirconium-Mediated Multicomponent Reactions of 1,3-Butadiynes with Ylidenemalononitriles to Form Functionalized 1,8-Naphthyridine and Cyclopenta[b]pyridine Derivatives
文献类型：期刊论文
| 作者 | Yu SS(俞莎莎); Sun RH(孙仁红); Chen HY(陈好益); Jie X(解鑫); Liu YH(刘元红) |
| 刊名 | Chem.-Eur. J.
 |
| 出版日期 | 2015 |
| 卷号 | 21期号:4页码:1420-1424 |
| 其他题名 | 锆促进的3-丁二炔与烯基双氰的多组分反应:官能团化1,8-萘啶和环戊烯并[b]吡啶衍生物的形成 |
| 通讯作者 | 刘元红 |
| 英文摘要 | Zirconocene-mediated multicomponent reactions of 1,3-butadiynes with ylidenemalononitriles in the absence or presence of CuCl have been developed. In the absence of CuCl, 1,3-butadiyne couples with three molecules of ylidenemalononitriles to yield azazirconacycles bearing a hexahydro-1,8-naphthyridine skeleton with high stereoselectivity. In the presence of CuCl, cyclopenta[b]pyridine or cyclopenta[b] quinolin-1-one derivatives are obtained via transmetalation of Zr-C bond to Cu-C bond as the key reaction step. These domino-type reactions proceed with high chemo-, regio- and/or stereoselectivities, and allowing the formation of multiple C-N and C-C bonds in a single operation. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/chem.201405899 |
| 语种 | 英语 |
| WOS记录号 | WOS:000347841500005 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39558]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Yu SS,Sun RH,Chen HY,et al. Zirconium-Mediated Multicomponent Reactions of 1,3-Butadiynes with Ylidenemalononitriles to Form Functionalized 1,8-Naphthyridine and Cyclopenta[b]pyridine Derivatives[J]. Chem.-Eur. J.,2015,21(4):1420-1424. |
| APA | 俞莎莎,孙仁红,陈好益,解鑫,&刘元红.(2015).Zirconium-Mediated Multicomponent Reactions of 1,3-Butadiynes with Ylidenemalononitriles to Form Functionalized 1,8-Naphthyridine and Cyclopenta[b]pyridine Derivatives.Chem.-Eur. J.,21(4),1420-1424. |
| MLA | 俞莎莎,et al."Zirconium-Mediated Multicomponent Reactions of 1,3-Butadiynes with Ylidenemalononitriles to Form Functionalized 1,8-Naphthyridine and Cyclopenta[b]pyridine Derivatives".Chem.-Eur. J. 21.4(2015):1420-1424. |
入库方式： OAI收割
来源：上海有机化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。