Highly Diastereo- and Enantioselective Palladium-Catalyzed [3+2] Cycloaddition of Vinyl Aziridines and alpha,beta-Unsaturated Ketones
文献类型：期刊论文
| 作者 | Xu CF(许超凡)1; Zheng BH(郑宝会)1; Suo JJ(索嘉嘉)1; Ding CH(丁昌华)1; Hou XL(侯雪龙)1 |
| 刊名 | Angew. Chem.-Int. Edit.
 |
| 出版日期 | 2015 |
| 卷号 | 54期号:5页码:1604-1607 |
| 其他题名 | 烯基氮杂环丙烷和a,b-不饱和酮的钯催化高非对映选择性, 高对映选择性[3+2]环加成反应 |
| 通讯作者 | 丁昌华 ; 侯雪龙 |
| 英文摘要 | A palladium-catalyzed asymmetric [3+2] cycloaddition reaction of vinylaziridines with alpha,beta-unsaturated ketones, wherein the alkenes have a single activator, is realized in high diastereo- and enantioselectivity, thus affording 3,4-disubstituted pyrrolidines in high yields with excellent ee values. The introduction of a methyl group at C1 of the vinyl group the vinylaziridines greatly improves the stereochemistry of the reaction. A plausible transition state is proposed. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/anie.201409467 |
| 语种 | 英语 |
| WOS记录号 | WOS:000348713900038 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39566]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.中科院上海有机化学研究所, 沪港合成化学联合实验室 |
| 推荐引用方式 GB/T 7714 | Xu CF,Zheng BH,Suo JJ,et al. Highly Diastereo- and Enantioselective Palladium-Catalyzed [3+2] Cycloaddition of Vinyl Aziridines and alpha,beta-Unsaturated Ketones[J]. Angew. Chem.-Int. Edit.,2015,54(5):1604-1607. |
| APA | 许超凡,郑宝会,索嘉嘉,丁昌华,&侯雪龙.(2015).Highly Diastereo- and Enantioselective Palladium-Catalyzed [3+2] Cycloaddition of Vinyl Aziridines and alpha,beta-Unsaturated Ketones.Angew. Chem.-Int. Edit.,54(5),1604-1607. |
| MLA | 许超凡,et al."Highly Diastereo- and Enantioselective Palladium-Catalyzed [3+2] Cycloaddition of Vinyl Aziridines and alpha,beta-Unsaturated Ketones".Angew. Chem.-Int. Edit. 54.5(2015):1604-1607. |
入库方式： OAI收割
来源：上海有机化学研究所
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