Highly Enantioselective Nickel-Catalyzed Intramolecular Reductive Cyclization of Alkynones
文献类型：期刊论文
| 作者 | Fu WZ(付文振); Nie M(聂明); Wang AZ(王爱珍); Cao ZP(曹子平); Tang WJ(汤文军) |
| 刊名 | Angew. Chem.-Int. Edit.
 |
| 出版日期 | 2015 |
| 卷号 | 54期号:8页码:2520-2524 |
| 其他题名 | 高立体选择性的分子内炔酮的还原环化 |
| 通讯作者 | 汤文军 |
| 英文摘要 | The first asymmetric nickel-catalyzed intramolecular reductive cyclization of alkynones is reported. A P-chiral monophosphine and triethylsilane were used as the ligand and the reducing reagent, respectively, to form a series of tertiary allylic alcohols bearing furan/pyran rings in excellent yields and enantioselectivities. This reaction has a broad substrate scope and enabled the efficient synthesis of dehydroxycubebin and chiral dibenzocyclooctadiene skeletons. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/anie.201410700 |
| 语种 | 英语 |
| WOS记录号 | WOS:000350100000040 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39569]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 生命有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Fu WZ,Nie M,Wang AZ,et al. Highly Enantioselective Nickel-Catalyzed Intramolecular Reductive Cyclization of Alkynones[J]. Angew. Chem.-Int. Edit.,2015,54(8):2520-2524. |
| APA | 付文振,聂明,王爱珍,曹子平,&汤文军.(2015).Highly Enantioselective Nickel-Catalyzed Intramolecular Reductive Cyclization of Alkynones.Angew. Chem.-Int. Edit.,54(8),2520-2524. |
| MLA | 付文振,et al."Highly Enantioselective Nickel-Catalyzed Intramolecular Reductive Cyclization of Alkynones".Angew. Chem.-Int. Edit. 54.8(2015):2520-2524. |
入库方式： OAI收割
来源：上海有机化学研究所
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