Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes
文献类型：期刊论文
| 作者 | Yuan ZL(袁浙梁); Wang HY(王昊阳); Mu X(慕欣); Guo YL(郭寅龙); Liu GS(刘国生) |
| 刊名 | J. Am. Chem. Soc.
 |
| 出版日期 | 2015 |
| 卷号 | 137期号:7页码:2468-2471 |
| 其他题名 | 钯催化苯乙烯的分子间高选择性氟硫化反应 |
| 通讯作者 | 刘国生 |
| 英文摘要 | A novel Pd-catalyzed intermolecular regio- and diastereoselective fluorosulfonylation of styrenes has been developed under mild conditions. This reaction exhibits a wide range of functional-group tolerance in styrenes and arylsulfinic acids to afford various beta-fluoro sulfones. Preliminary mechanistic study reveals an unusual mechanism, in which a high-valent (L2PdF)-F-III species side-selectively reacts with a benzylic carbon radical to deliver a C-F bond. This pathway is distinct from a previously reported radical fluorination reaction. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ja5131676 |
| 语种 | 英语 |
| WOS记录号 | WOS:000350192700015 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39578]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Yuan ZL,Wang HY,Mu X,et al. Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes[J]. J. Am. Chem. Soc.,2015,137(7):2468-2471. |
| APA | 袁浙梁,王昊阳,慕欣,郭寅龙,&刘国生.(2015).Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes.J. Am. Chem. Soc.,137(7),2468-2471. |
| MLA | 袁浙梁,et al."Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes".J. Am. Chem. Soc. 137.7(2015):2468-2471. |
入库方式： OAI收割
来源：上海有机化学研究所
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