Rh-II-Catalyzed [3+2] Cycloaddition of 2H-Azirines with N-Sulfonyl-1,2,3-Triazoles
文献类型：期刊论文
| 作者 | Zhao YZ(赵允州); Yang HB(杨海斌); Tang XY(唐翔鹰); Shi M(施敏) |
| 刊名 | Chem.-Eur. J.
 |
| 出版日期 | 2015 |
| 卷号 | 21期号:9页码:3562-3566 |
| 其他题名 | 铑(II)催化的氮杂三元环和三氮唑的[3+2]环加成反应 |
| 通讯作者 | 唐翔鹰 ; 施敏 |
| 英文摘要 | Rh-II-catalyzed intermolecular [3+2] cycloaddition of 2H-azirines with N-sulfonyl-1,2,3-triazoles is disclosed, in which a series of fully functionalized pyrroles is produced via rhodium azavinyl carbene intermediates. A distinct feature of this reaction is that the azavinyl carbene serves as a [2C] equivalent, instead of as [1C] or aza-[3C] synthons, which have been reported previously in cyclopropanations and [3+n] cycloadditions. Moreover, this methodology has also been successfully applied in the total synthesis of URB447 as well as the formal synthesis of Atorvastatin (Lipitor). |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/chem.201406460 |
| 语种 | 英语 |
| WOS记录号 | WOS:000350116200010 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39580]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhao YZ,Yang HB,Tang XY,et al. Rh-II-Catalyzed [3+2] Cycloaddition of 2H-Azirines with N-Sulfonyl-1,2,3-Triazoles[J]. Chem.-Eur. J.,2015,21(9):3562-3566. |
| APA | 赵允州,杨海斌,唐翔鹰,&施敏.(2015).Rh-II-Catalyzed [3+2] Cycloaddition of 2H-Azirines with N-Sulfonyl-1,2,3-Triazoles.Chem.-Eur. J.,21(9),3562-3566. |
| MLA | 赵允州,et al."Rh-II-Catalyzed [3+2] Cycloaddition of 2H-Azirines with N-Sulfonyl-1,2,3-Triazoles".Chem.-Eur. J. 21.9(2015):3562-3566. |
入库方式： OAI收割
来源：上海有机化学研究所
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