Rhodium-catalyzed C-H functionalization-based approach to eight-membered lactams
文献类型：期刊论文
| 作者 | Wu SZ(吴尚泽)1; Ceng R(曾荣)1; Fu CL(傅春玲)1; Yu YH(余亦华)1; Zhang X(张雪)1; Ma SM(麻生明)1 |
| 刊名 | Chem. Sci.
 |
| 出版日期 | 2015 |
| 卷号 | 6期号:4页码:2275-2285 |
| 其他题名 | 铑催化的通过C-H键活化合成八元内酰胺的方法 |
| 通讯作者 | 张雪 ; 麻生明 |
| 英文摘要 | A Rh(III) catalyzed formal [4 + 2 + 2] cyclization of N-pivaloyloxybenzamides 1 with 1,6-allene-enes 2 by C-H functionalization is reported. The reactions occur at room temperature and are compatible with air and moisture with a tolerance of many synthetically useful functional groups. The follow-up modifications of the products have been demonstrated. After careful mechanistic studies and DFT calculation, a reaction mechanism was proposed. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/c5sc00092k |
| 语种 | 英语 |
| WOS记录号 | WOS:000351412800016 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39584]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.浙江大学 2.中科院上海有机化学研究所, 金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Wu SZ,Ceng R,Fu CL,et al. Rhodium-catalyzed C-H functionalization-based approach to eight-membered lactams[J]. Chem. Sci.,2015,6(4):2275-2285. |
| APA | 吴尚泽,曾荣,傅春玲,余亦华,张雪,&麻生明.(2015).Rhodium-catalyzed C-H functionalization-based approach to eight-membered lactams.Chem. Sci.,6(4),2275-2285. |
| MLA | 吴尚泽,et al."Rhodium-catalyzed C-H functionalization-based approach to eight-membered lactams".Chem. Sci. 6.4(2015):2275-2285. |
入库方式： OAI收割
来源：上海有机化学研究所
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