Palladium-Catalyzed Intramolecular Aminoacetoxylation of Unactivated Alkenes with Hydrogen Peroxide as Oxidant
文献类型：期刊论文
| 作者 | Zhu HT(朱海涛); Chen PH(陈品红); Liu GS(刘国生) |
| 刊名 | Org. Lett.
 |
| 出版日期 | 2015 |
| 卷号 | 17期号:6页码:1485-1488 |
| 其他题名 | 钯催化非活性烯烃的分子内胺乙酰基化反应 |
| 通讯作者 | 刘国生 |
| 英文摘要 | A palladium-catalyzed intramolecular aminoacetoxylation of unactivated alkenes was developed in which H2O2 was used as the sole oxidant. A variety of 3-acetoxylated piperidines were obtained in good yields with good to excellent regio- and diastereoselectivities. Mechanistic study revealed that the addition of di(2-pyridyl) ketone (dpk) ligand was crucial to promote the oxidative cleavage of the C-Pd(II) bond by H2O2 to give the C-OAc bond. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/acs.orglett.5b00373 |
| 语种 | 英语 |
| WOS记录号 | WOS:000351558100035 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39585]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhu HT,Chen PH,Liu GS. Palladium-Catalyzed Intramolecular Aminoacetoxylation of Unactivated Alkenes with Hydrogen Peroxide as Oxidant[J]. Org. Lett.,2015,17(6):1485-1488. |
| APA | 朱海涛,陈品红,&刘国生.(2015).Palladium-Catalyzed Intramolecular Aminoacetoxylation of Unactivated Alkenes with Hydrogen Peroxide as Oxidant.Org. Lett.,17(6),1485-1488. |
| MLA | 朱海涛,et al."Palladium-Catalyzed Intramolecular Aminoacetoxylation of Unactivated Alkenes with Hydrogen Peroxide as Oxidant".Org. Lett. 17.6(2015):1485-1488. |
入库方式： OAI收割
来源：上海有机化学研究所
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