Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H-2 and CO2
文献类型：期刊论文
| 作者 | Zhang L(张磊); Han ZB(韩召斌); Zhao XY(赵骁宇); Wang Z(王正); Ding KL(丁奎岭) |
| 刊名 | Angew. Chem.-Int. Edit.
 |
| 出版日期 | 2015 |
| 卷号 | 54期号:21页码:6186-6189 |
| 其他题名 | 钌催化的用二氧化碳和氢气对胺的高效N-甲酰化反应 |
| 通讯作者 | 丁奎岭 |
| 英文摘要 | A highly efficient catalyst system based on ruthenium-pincer-type complexes has been discovered for N-formylation of various amines with CO2 and H-2, thus affording the corresponding formamides with excellent productivity (turnover numbers of up to 1940000 in a single batch) and selectivity. Using a simple catalyst recycling protocol, the catalyst was reused for 12 runs in N,N-dimethylformamide production without significant loss of activity, thus demonstrating the potential for practical utilization of this cost-effective process. A one-pot two-step procedure for hydrogenation of CO2 to methanol via the intermediacy of formamide formation has also been developed. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/anie.201500939 |
| 语种 | 英语 |
| WOS记录号 | WOS:000354260000011 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39596]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhang L,Han ZB,Zhao XY,et al. Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H-2 and CO2[J]. Angew. Chem.-Int. Edit.,2015,54(21):6186-6189. |
| APA | 张磊,韩召斌,赵骁宇,王正,&丁奎岭.(2015).Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H-2 and CO2.Angew. Chem.-Int. Edit.,54(21),6186-6189. |
| MLA | 张磊,et al."Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H-2 and CO2".Angew. Chem.-Int. Edit. 54.21(2015):6186-6189. |
入库方式： OAI收割
来源：上海有机化学研究所
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