Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond
文献类型：期刊论文
| 作者 | Sun J(孙键)1; Ou C(欧翀)1; Wang C(王超)1; UCHIYAMA MASANOBU1; Deng L(邓亮)1 |
| 刊名 | Organometallics
 |
| 出版日期 | 2015 |
| 卷号 | 34期号:8页码:1546-1551 |
| 其他题名 | 具有共价钴硅键的五配位硅的硅基官能团化的氮杂环卡宾钴配合物 |
| 通讯作者 | 王超 ; 邓亮 |
| 英文摘要 | Novel cobalt complexes featuring five-coordinate silicon centers with a covalent CoSi bond, i.e., [(SiN2C)Co(OPy)] complexes (SiN2C = tetradentate silane-anchored bis(pyridine)-N-heterocyclic carbene (NHC) ligand, OPy = 2-pyridonato), were prepared by reaction of bidentate hydrosilyl-NHC-supported cobalt(II) complexes with 2-pyridone and characterized by H-1, C-13, and Si-29 NMR, single-crystal X-ray diffraction, and elemental analyses. Theoretical calculations support a covalent nature of the CoSi interaction, in contrast to the metal -> Si dative bonds in metallasilatranes. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/acs.organomet.5b00114 |
| 语种 | 英语 |
| WOS记录号 | WOS:000353668700015 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39598]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.日本理化学研究所 3.日本东京大学 |
| 推荐引用方式 GB/T 7714 | Sun J,Ou C,Wang C,et al. Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond[J]. Organometallics,2015,34(8):1546-1551. |
| APA | 孙键,欧翀,王超,UCHIYAMA MASANOBU,&邓亮.(2015).Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond.Organometallics,34(8),1546-1551. |
| MLA | 孙键,et al."Silane-Functionalized N-Heterocyclic Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond".Organometallics 34.8(2015):1546-1551. |
入库方式： OAI收割
来源：上海有机化学研究所
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