Efficient production of methanol and diols via the hydrogenation of cyclic carbonates using copper-silica nanocomposite catalysts
文献类型：期刊论文
| 作者 | Liu HL(刘海龙)1; Huang ZW(黄志伟)1; Han ZB(韩召斌)1; Ding KL(丁奎岭)1; Liu HC(刘海超)1; Xia CG(夏春谷)1; Chen J(陈经)1 |
| 刊名 | Green Chem.
 |
| 出版日期 | 2015 |
| 卷号 | 17期号:8页码:4281-4290 |
| 其他题名 | 铜-硅酸盐纳米复合催化剂催化的环状碳酸酯氢化高效制备甲醇和二醇 |
| 通讯作者 | 丁奎岭 ; 夏春谷 ; 陈经 |
| 英文摘要 | Copper-silica nanocomposite catalysts with a uniform Cu dispersion prepared by a precipitation-gel method have been found to be highly efficient in the heterogeneous catalytic hydrogenation of CO2-derived cyclic carbonates, providing an indirect but practical approach for the transformation of CO2 to methanol with the co-production of diols under relatively mild conditions. The catalysts possessed remarkable stability in both batch and fixed-bed continuous flow reactors especially after promotion with B2O3. The reaction was found to depend sensitively on the Cu particle size, the surface acidity-basicity and the Cu valence of the catalysts. The synergetic effect between balanced Cu-0 and Cu+ sites was considered to play a critical role in attaining high yields of methanol and diols. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/c5gc00810g |
| 语种 | 英语 |
| WOS记录号 | WOS:000358887300023 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39629]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.中科院兰州化学物理研究所 2.中科院上海有机化学研究所, 金属有机化学国家重点实验室 3.中国科学院大学 |
| 推荐引用方式 GB/T 7714 | Liu HL,Huang ZW,Han ZB,et al. Efficient production of methanol and diols via the hydrogenation of cyclic carbonates using copper-silica nanocomposite catalysts[J]. Green Chem.,2015,17(8):4281-4290. |
| APA | 刘海龙.,黄志伟.,韩召斌.,丁奎岭.,刘海超.,...&陈经.(2015).Efficient production of methanol and diols via the hydrogenation of cyclic carbonates using copper-silica nanocomposite catalysts.Green Chem.,17(8),4281-4290. |
| MLA | 刘海龙,et al."Efficient production of methanol and diols via the hydrogenation of cyclic carbonates using copper-silica nanocomposite catalysts".Green Chem. 17.8(2015):4281-4290. |
入库方式： OAI收割
来源：上海有机化学研究所
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