Gold(I)-catalyzed cycloisomerization of vinylidenecyclopropane-enes via carbene or non-carbene processes
文献类型：期刊论文
| 作者 | Li DY(李德尧)1; Wei Y(魏音)1; MAREK ILAN1; Tang XY(唐翔鹰)1; Shi M(施敏)1 |
| 刊名 | Chem. Sci.
 |
| 出版日期 | 2015 |
| 卷号 | 6期号:10页码:5519-5525 |
| 其他题名 | 金催化的亚乙烯基环丙烷的环异构化反应 |
| 通讯作者 | 唐翔鹰 ; 施敏 |
| 英文摘要 | Gold catalyzed cycloisomerization of aromatic ring tethered vinylidenecyclopropane-enes provides a divergent synthetic protocol for the construction of O-containing fused heterocycles through controllable carbene or non-carbene related processes. The carbene induced process features a new amphiphilic strategy to generate a gold carbene via a rearrangement of vinylidenecyclopropane. Whereas, the electronic effect of the ortho-substituents switches the reaction mode onto the non-carbene related process, from which five-or six-membered rings are selectively produced through allyl-migration. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/c5sc01806d |
| 语种 | 英语 |
| WOS记录号 | WOS:000361212000020 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39639]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.以色列理工学院 |
| 推荐引用方式 GB/T 7714 | Li DY,Wei Y,MAREK ILAN,et al. Gold(I)-catalyzed cycloisomerization of vinylidenecyclopropane-enes via carbene or non-carbene processes[J]. Chem. Sci.,2015,6(10):5519-5525. |
| APA | 李德尧,魏音,MAREK ILAN,唐翔鹰,&施敏.(2015).Gold(I)-catalyzed cycloisomerization of vinylidenecyclopropane-enes via carbene or non-carbene processes.Chem. Sci.,6(10),5519-5525. |
| MLA | 李德尧,et al."Gold(I)-catalyzed cycloisomerization of vinylidenecyclopropane-enes via carbene or non-carbene processes".Chem. Sci. 6.10(2015):5519-5525. |
入库方式： OAI收割
来源：上海有机化学研究所
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