Substitution reaction of triphenylphosphine oxide with rare-earth metal phosphido methyl complexes
文献类型：期刊论文
| 作者 | Lv YD(吕英东); Zhou JL(周吉亮); Leng XB(冷雪冰); Chen YF(陈耀峰) |
| 刊名 | New J. Chem.
 |
| 出版日期 | 2015 |
| 卷号 | 39期号:10页码:7582-7588 |
| 其他题名 | 三苯基氧膦和稀土膦基甲基配合物间的取代反应 |
| 通讯作者 | 陈耀峰 |
| 英文摘要 | Rare-earth metal phosphido methyl complexes, [LLn(Me){P(H)Ar}] (L = [MeC{N(DIPP)}CHC(Me)(NCH2CH2NMe2)](-), DIPP = 2,6-(Pr2C6H3)-Pr-i; 1: Ln = Sc, Ar = 2,4,6-(Bu3C6H2)-Bu-t; 2: Ln = Sc, Ar = 2,6-(Pr2C6H3)-Pr-i; 3: Ln = Sc, Ar = 2,6-Me2C6H3; 4: Ln = Lu, Ar = 2,4,6-(Bu3C6H2)-Bu-t; 5: Ln = Lu, Ar = 2,6-(Pr2C6H3)-Pr-i), were synthesized and characterized. Complexes 1-5 reacted with triphenylphosphine oxide (Ph3P=O) to give[LLn(Ph){CH2P(O)Ph-2}] (Ln = Sc(6), Lu(7)), by a mechanism that includes C(alkyl)-P bond formation and C(aryl)-P bond cleavage. The molecular structures of 1, 3 and 7 were determined by single-crystal X-ray diffraction. A pathway for the formation of 6 and 7 was suggested. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/c5nj00335k |
| 语种 | 英语 |
| WOS记录号 | WOS:000362355200010 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39645]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Lv YD,Zhou JL,Leng XB,et al. Substitution reaction of triphenylphosphine oxide with rare-earth metal phosphido methyl complexes[J]. New J. Chem.,2015,39(10):7582-7588. |
| APA | 吕英东,周吉亮,冷雪冰,&陈耀峰.(2015).Substitution reaction of triphenylphosphine oxide with rare-earth metal phosphido methyl complexes.New J. Chem.,39(10),7582-7588. |
| MLA | 吕英东,et al."Substitution reaction of triphenylphosphine oxide with rare-earth metal phosphido methyl complexes".New J. Chem. 39.10(2015):7582-7588. |
入库方式： OAI收割
来源：上海有机化学研究所
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