A General, Practical Triethylborane-Catalyzed Reduction of Carbonyl Functions to Alcohols
文献类型：期刊论文
| 作者 | Peng DJ(彭东杰); Zhang MT(张岷涛); Huang Z(黄正) |
| 刊名 | Chem.-Eur. J.
 |
| 出版日期 | 2015 |
| 卷号 | 21期号:42页码:14737-14741 |
| 其他题名 | 一种普遍并实用的三乙基硼催化含官能团的羰基还原为醇的方法 |
| 通讯作者 | 黄正 |
| 英文摘要 | A combination of the abundant and low-cost triethylborane and sodium alkoxide generates a highly efficient catalyst for reduction of esters, as well as ketones and aldehydes, to alcohols using an inexpensive hydrosilane under mild conditions. The catalyst system exhibits excellent chemoselectivity and a high level of functional group tolerance. Mechanistic studies revealed a resting state of sodium triethylalkoxylborate that is the product of the reaction of BEt3 with sodium alkoxide. This borate species reacts with hydrosilane to form NaBEt3H, which rapidly reduces esters. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/chem.201502942 |
| 语种 | 英语 |
| WOS记录号 | WOS:000363331900011 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39649]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Peng DJ,Zhang MT,Huang Z. A General, Practical Triethylborane-Catalyzed Reduction of Carbonyl Functions to Alcohols[J]. Chem.-Eur. J.,2015,21(42):14737-14741. |
| APA | 彭东杰,张岷涛,&黄正.(2015).A General, Practical Triethylborane-Catalyzed Reduction of Carbonyl Functions to Alcohols.Chem.-Eur. J.,21(42),14737-14741. |
| MLA | 彭东杰,et al."A General, Practical Triethylborane-Catalyzed Reduction of Carbonyl Functions to Alcohols".Chem.-Eur. J. 21.42(2015):14737-14741. |
入库方式： OAI收割
来源：上海有机化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。