Asymmetric Construction of Six-Membered Rings by Cyclization of Allenes with Dinuclear Gold Catalysis
文献类型：期刊论文
| 作者 | Chou YA(仇友爱)1; Zhou J(周静)1; Li JZ(李军召)1; Fu CL(傅春玲)1; Guo YL(郭寅龙)1; Wang HY(王浩洋)1; Ma SM(麻生明)1 |
| 刊名 | Chem.-Eur. J.
 |
| 出版日期 | 2015 |
| 卷号 | 21期号:45页码:15939-15943 |
| 其他题名 | 通过金催化的联烯环化反应构建六元环的方法 |
| 通讯作者 | 王浩洋 ; 麻生明 |
| 英文摘要 | A simple and efficient method for the synthesis of 1,4-dihydroarenes by gold-catalyzed 6-endo cyclization of benzylic allenes has been developed. Furthermore, asymmetric hydroarylation of enantioenriched allenes has been realized to offer a practical and convergent approach to aromatic ring-fused six-membered cycles containing a chiral stereocenter such as 1,4-dihydronaphthalenes, 1,4-dihydrodibenzo[b,d]thiophenes, and 4,7-dihydrobenzo[b]thiophenes by applying dinuclear [(dppm)Au2Cl2] [dppm=methylenebis(diphenylphosphane)] combined with AgOTf as the catalyst to ensure the high efficiency of chirality transfer. ESI-MS has been applied to characterize some of the key reactive dinuclear gold intermediates successfully. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/chem.201503179 |
| 语种 | 英语 |
| WOS记录号 | WOS:000363890700010 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39650]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.浙江大学 2.中科院上海有机化学研究所, 金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Chou YA,Zhou J,Li JZ,et al. Asymmetric Construction of Six-Membered Rings by Cyclization of Allenes with Dinuclear Gold Catalysis[J]. Chem.-Eur. J.,2015,21(45):15939-15943. |
| APA | 仇友爱.,周静.,李军召.,傅春玲.,郭寅龙.,...&麻生明.(2015).Asymmetric Construction of Six-Membered Rings by Cyclization of Allenes with Dinuclear Gold Catalysis.Chem.-Eur. J.,21(45),15939-15943. |
| MLA | 仇友爱,et al."Asymmetric Construction of Six-Membered Rings by Cyclization of Allenes with Dinuclear Gold Catalysis".Chem.-Eur. J. 21.45(2015):15939-15943. |
入库方式： OAI收割
来源：上海有机化学研究所
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