Zwitterionic Nickel(II) Catalyst for CO-Ethylene Alternating Copolymerization
文献类型：期刊论文
| 作者 | Jia XF(贾肖飞)1; Zhang MR(张梦如)1; Pan F(潘璠)1; BABAHAN ILKNUR1; Ding KL(丁奎岭)1; Jia L(贾力)1; CRANDALL LAURA A1; ZIEGLER CHRISTOPHER J1 |
| 刊名 | Organometallics
 |
| 出版日期 | 2015 |
| 卷号 | 34期号:20页码:4798-4801 |
| 其他题名 | 两性离子-镍(II)催化剂催化的一氧化碳-乙烯交替共聚 |
| 通讯作者 | 贾力 |
| 英文摘要 | A zwitterionic nickel(II) catalyst has been discovered to display an initial catalytic activity comparable to that of cationic palladium catalysts for alternating copolymerization of carbon monoxide and ethylene. This demonstrates the absence of a severe dormant state in the present zwitterionic system, in contrast to the cationic nickel(II) catalysts. However, the highly active catalyst is short-lived. Stoichiometric decomposition of the catalyst under carbon monoxide suggests that the insufficient stability of the tetraphenylborate motif in the ligand framework with respect to electrophilic attack is likely a culprit for catalyst deactivation. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/acs.organomet.5b00676 |
| 语种 | 英语 |
| WOS记录号 | WOS:000363996300004 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39651]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.美国阿克伦大学 2.中科院上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Jia XF,Zhang MR,Pan F,et al. Zwitterionic Nickel(II) Catalyst for CO-Ethylene Alternating Copolymerization[J]. Organometallics,2015,34(20):4798-4801. |
| APA | 贾肖飞.,张梦如.,潘璠.,BABAHAN ILKNUR.,丁奎岭.,...&ZIEGLER CHRISTOPHER J.(2015).Zwitterionic Nickel(II) Catalyst for CO-Ethylene Alternating Copolymerization.Organometallics,34(20),4798-4801. |
| MLA | 贾肖飞,et al."Zwitterionic Nickel(II) Catalyst for CO-Ethylene Alternating Copolymerization".Organometallics 34.20(2015):4798-4801. |
入库方式： OAI收割
来源：上海有机化学研究所
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