Zinc diiodide-promoted synthesis of trisubstituted allenes from propargylic amines
文献类型：期刊论文
| 作者 | Kuang JQ(况锦强)1; Tang XJ(汤鑫军)1; Ma SM(麻生明)1 |
| 刊名 | Org. Chem. Front.
 |
| 出版日期 | 2015 |
| 卷号 | 2期号:5页码:470-475 |
| 其他题名 | 二碘化锌促进的从丙炔胺出发合成三取代联烯的方法 |
| 通讯作者 | 麻生明 |
| 英文摘要 | Zinc diiodide has been identified as an effective reagent for the efficient synthesis of trisubstituted allenes from propargylic amines. Compared to CdI2 this protocol offers a green approach. Due to the easy preparation of propargylic amines through the method developed by this group, this method provides a two-step synthesis of trisubstituted allenes from 1-alkynes, ketones, and pyrrolidine. Finally, an efficient synthesis of such trisubstituted allenes from 1-alkynes, ketones, and pyrrolidine via simple filtration has been developed. Compared with the CdI2-mediated protocol, the current protocol enjoys a much wider scope for ketones and affords functionalized allenes without further cyclization in some substrates. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/c5qo00047e |
| 语种 | 英语 |
| WOS记录号 | WOS:000364445300003 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39659]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.复旦大学 |
| 推荐引用方式 GB/T 7714 | Kuang JQ,Tang XJ,Ma SM. Zinc diiodide-promoted synthesis of trisubstituted allenes from propargylic amines[J]. Org. Chem. Front.,2015,2(5):470-475. |
| APA | 况锦强,汤鑫军,&麻生明.(2015).Zinc diiodide-promoted synthesis of trisubstituted allenes from propargylic amines.Org. Chem. Front.,2(5),470-475. |
| MLA | 况锦强,et al."Zinc diiodide-promoted synthesis of trisubstituted allenes from propargylic amines".Org. Chem. Front. 2.5(2015):470-475. |
入库方式： OAI收割
来源：上海有机化学研究所
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