CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes
文献类型：期刊论文
| 作者 | Tang XJ(汤鑫军)1; Huang X(黄鑫)1; Cao T(曹陶)1; Han YL(韩玉林)1; Jiang XG(姜兴国)1; Lin WL(林渭龙)1; Tang Y(唐阳)1; Zhang JS(张加生)1; Yu Q(俞琼)1; Fu CL(傅春玲)1 |
| 刊名 | Org. Chem. Front.
 |
| 出版日期 | 2015 |
| 卷号 | 2期号:6页码:688-691 |
| 其他题名 | CuBr2催化的对映选择性合成高官能团化的天然产物联烯的方法 |
| 通讯作者 | 麻生明 |
| 英文摘要 | Here we show the CuBr2-catalyzed approach for highly enantioselective synthesis (90-98% ee) of allenes bearing a very broad array of unmasked synthetically attractive functionalities from aldehydes and terminal alkynyl bearing reactive functionalities with the absolute configuration controlled by applying readily available (R)- or ( S)-alpha,alpha-diphenylprolinol. Following this protocol, the highly enantioselective synthesis of some naturally occurring allenes loaded with reactive functionalities becomes simple: a terminal alkyne plus an aldehyde. In comparison, they were reported to be synthesized either from similar level generic chemicals with much more steps or in lower ees. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/c5qo00084j |
| 语种 | 英语 |
| WOS记录号 | WOS:000364445900012 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39661]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.浙江大学 3.华东师范大学 |
| 推荐引用方式 GB/T 7714 | Tang XJ,Huang X,Cao T,et al. CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes[J]. Org. Chem. Front.,2015,2(6):688-691. |
| APA | 汤鑫军.,黄鑫.,曹陶.,韩玉林.,姜兴国.,...&麻生明.(2015).CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes.Org. Chem. Front.,2(6),688-691. |
| MLA | 汤鑫军,et al."CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes".Org. Chem. Front. 2.6(2015):688-691. |
入库方式： OAI收割
来源：上海有机化学研究所
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