Efficient synthesis of P-chiral biaryl phosphonates by stereoselective intramolecular cyclization
文献类型：期刊论文
| 作者 | Xu GQ(徐广庆); Li MH(李明洪); Wang SL(王守亮); Tang WJ(汤文军) |
| 刊名 | Org. Chem. Front.
 |
| 出版日期 | 2015 |
| 卷号 | 2期号:10页码:1342-1345 |
| 其他题名 | 利用不对称环化反应高效合成P-手性联芳基磷酸酯的方法 |
| 通讯作者 | 汤文军 |
| 英文摘要 | A series of P-chiral biaryl phosphonates were efficiently synthesized from diaryl 2-bromo arylphosphonates in high yields (up to 92%) and good enantioselectivities (up to 88% ee) through a palladium-catalyzed asymmetric cyclization with a novel P-chiral biaryl monophosphorus ligand. The P-chiral biaryl phosphonate can be rapidly transformed to both antipodes of a P-chiral dialkyl biaryl monophosphorus structure. The method provides a convenient access to various P-chiral biaryl monophosphines. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/c5qo00142k |
| 语种 | 英语 |
| WOS记录号 | WOS:000364450000008 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39667]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 生命有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Xu GQ,Li MH,Wang SL,et al. Efficient synthesis of P-chiral biaryl phosphonates by stereoselective intramolecular cyclization[J]. Org. Chem. Front.,2015,2(10):1342-1345. |
| APA | 徐广庆,李明洪,王守亮,&汤文军.(2015).Efficient synthesis of P-chiral biaryl phosphonates by stereoselective intramolecular cyclization.Org. Chem. Front.,2(10),1342-1345. |
| MLA | 徐广庆,et al."Efficient synthesis of P-chiral biaryl phosphonates by stereoselective intramolecular cyclization".Org. Chem. Front. 2.10(2015):1342-1345. |
入库方式： OAI收割
来源：上海有机化学研究所
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