Minimizing Aryloxy Elimination in Rh-I-Catalyzed Asymmetric Hydrogenation of -Aryloxyacrylic Acids using a Mixed-Ligand Strategy
文献类型：期刊论文
| 作者 | Li Y(李洋)1; Wang Z(王正)1; Ding KL(丁奎岭)1 |
| 刊名 | Chem.-Eur. J.
 |
| 出版日期 | 2015 |
| 卷号 | 21期号:46页码:16387-16390 |
| 其他题名 | 用混合配体策略抑制铑(I)催化β-芳氧基丙烯酸不对称氢化中的芳氧消除 |
| 通讯作者 | 丁奎岭 |
| 英文摘要 | The first example of efficient asymmetric hydrogenation of challenging -aryloxyacrylic acids was realized using a Rh-I-complex based on the heterocombination of a readily available chiral monodentate secondary phosphine oxide (SPO) and an achiral monodentate phosphine ligand as the catalyst. Excellent enantioselectivities (92->99% ee) were achieved for a wide variety of chiral -aryloxypropionic acids with minor aryloxy elimination in most cases. The resultant products were readily transformed into biologically active compounds through simple synthetic manipulations. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/chem.201503229 |
| 语种 | 英语 |
| WOS记录号 | WOS:000365132100014 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39670]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.天津化学化工协同创新中心 |
| 推荐引用方式 GB/T 7714 | Li Y,Wang Z,Ding KL. Minimizing Aryloxy Elimination in Rh-I-Catalyzed Asymmetric Hydrogenation of -Aryloxyacrylic Acids using a Mixed-Ligand Strategy[J]. Chem.-Eur. J.,2015,21(46):16387-16390. |
| APA | 李洋,王正,&丁奎岭.(2015).Minimizing Aryloxy Elimination in Rh-I-Catalyzed Asymmetric Hydrogenation of -Aryloxyacrylic Acids using a Mixed-Ligand Strategy.Chem.-Eur. J.,21(46),16387-16390. |
| MLA | 李洋,et al."Minimizing Aryloxy Elimination in Rh-I-Catalyzed Asymmetric Hydrogenation of -Aryloxyacrylic Acids using a Mixed-Ligand Strategy".Chem.-Eur. J. 21.46(2015):16387-16390. |
入库方式： OAI收割
来源：上海有机化学研究所
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