Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones
文献类型：期刊论文
| 作者 | Wang D(王德)1; Wang GP(王国鹏)1; Sun YL(孙姚良)1; Zhu SF(朱守非)1; Wei Y(魏音)1; Zhou QL(周其林)1; Shi M(施敏)1 |
| 刊名 | Chem. Sci.
 |
| 出版日期 | 2015 |
| 卷号 | 6期号:12页码:7319-7325 |
| 其他题名 | 手性膦催化的高区域和高对映选择性环化反应研究-构建螺环骨架的苯并呋喃类化合物 |
| 通讯作者 | 魏音 ; 周其林 ; 施敏 |
| 英文摘要 | The first regioselective catalytic asymmetric [3 + 2] cycloaddition of benzofuranone-derived olefins with allenoates and substituted allenoates has been developed in the presence of (R)-SITCP, affording different functionalized 3-spirocyclopentene benzofuran-2-ones in good yields with high enantioselectivities under mild conditions. The substrate scope has also been examined. The regioselective outcomes for this phosphine-catalyzed [3 + 2] cycloaddition reaction can be rationalized using DFT calculations. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/c5sc03135d |
| 语种 | 英语 |
| WOS记录号 | WOS:000365225300076 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39672]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.南开大学 |
| 推荐引用方式 GB/T 7714 | Wang D,Wang GP,Sun YL,et al. Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones[J]. Chem. Sci.,2015,6(12):7319-7325. |
| APA | 王德.,王国鹏.,孙姚良.,朱守非.,魏音.,...&施敏.(2015).Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones.Chem. Sci.,6(12),7319-7325. |
| MLA | 王德,et al."Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones".Chem. Sci. 6.12(2015):7319-7325. |
入库方式： OAI收割
来源：上海有机化学研究所
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