Gold-Catalyzed Synthesis of Tropone and Its Analogues via Oxidative Ring Expansion of Alkynyl Quinols
文献类型:期刊论文
作者 | Zhao JD(赵继东); Liu J(刘俊); Jie X(解鑫); Li S(李石); Liu YH(刘元红) |
刊名 | Org. Lett.
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出版日期 | 2015 |
卷号 | 17期号:23页码:5926-5929 |
其他题名 | 金催化炔基对苯二酚的氧化扩环反应: 环庚三烯酮及其类似物的合成 |
通讯作者 | 李石 ; 刘元红 |
英文摘要 | A new and convenient strategy for the synthesis of functionalized tropone derivatives based on the gold-catalyzed oxidative ring expansion of alkynyl quinols has been developed. The reaction proceeds via gold-catalyzed highly regioselective oxidation followed by 1,2-migration of a vinyl or phenyl group. Extension of this chemistry allows ready access to various seven- or six-membered ring systems such as benzotropones, benzooxepines, phenanthrenes, and quinolin-2(1H)-ones. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/acs.orglett.5b03160 |
语种 | 英语 |
WOS记录号 | WOS:000366152000052 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39674] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
作者单位 | 中科院上海有机化学研究所, 金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Zhao JD,Liu J,Jie X,et al. Gold-Catalyzed Synthesis of Tropone and Its Analogues via Oxidative Ring Expansion of Alkynyl Quinols[J]. Org. Lett.,2015,17(23):5926-5929. |
APA | 赵继东,刘俊,解鑫,李石,&刘元红.(2015).Gold-Catalyzed Synthesis of Tropone and Its Analogues via Oxidative Ring Expansion of Alkynyl Quinols.Org. Lett.,17(23),5926-5929. |
MLA | 赵继东,et al."Gold-Catalyzed Synthesis of Tropone and Its Analogues via Oxidative Ring Expansion of Alkynyl Quinols".Org. Lett. 17.23(2015):5926-5929. |
入库方式: OAI收割
来源:上海有机化学研究所
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