The Renaissance of an Old Problem: Highly Regioselective Carboxylation of 2-Alkynyl Bromides with Carbon Dioxide
文献类型：期刊论文
| 作者 | 缪不可言1; Li G(李根)1; Ma SM(麻生明)1 |
| 刊名 | Chem.-Eur. J.
 |
| 出版日期 | 2015 |
| 卷号 | 21期号:48页码:17224-17228 |
| 其他题名 | 高对映选择性的2-炔基溴和二氧化碳的羧化反应 |
| 通讯作者 | 麻生明 |
| 英文摘要 | A steric effect-controlled, zinc-mediated carboxylation of different 2-alkynyl bromides under an atmospheric pressure of CO2 has been developed by careful tuning of different reaction parameters, including the metal, solvent, temperature, and additive. 2-Substituted 2,3-allenoic acids were afforded from primary 2-alkynyl bromides, whereas the carboxylation of secondary 2-alkynyl bromides yielded 3-alkynoic acids in decent yields. A rationale for the observed regioselectivity has been proposed. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/chem.201503494 |
| 语种 | 英语 |
| WOS记录号 | WOS:000366510900012 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39677]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 1.华东师范大学 2.复旦大学 3.中科院上海有机化学研究所, 金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | 缪不可言,Li G,Ma SM. The Renaissance of an Old Problem: Highly Regioselective Carboxylation of 2-Alkynyl Bromides with Carbon Dioxide[J]. Chem.-Eur. J.,2015,21(48):17224-17228. |
| APA | 缪不可言,李根,&麻生明.(2015).The Renaissance of an Old Problem: Highly Regioselective Carboxylation of 2-Alkynyl Bromides with Carbon Dioxide.Chem.-Eur. J.,21(48),17224-17228. |
| MLA | 缪不可言,et al."The Renaissance of an Old Problem: Highly Regioselective Carboxylation of 2-Alkynyl Bromides with Carbon Dioxide".Chem.-Eur. J. 21.48(2015):17224-17228. |
入库方式： OAI收割
来源：上海有机化学研究所
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