Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes
文献类型：期刊论文
| 作者 | CHEN CHAOHUANG; Chen PH(陈品红); Liu GS(刘国生) |
| 刊名 | J. Am. Chem. Soc.
 |
| 出版日期 | 2015 |
| 卷号 | 137期号:50页码:15648-15651 |
| 其他题名 | Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes |
| 通讯作者 | 刘国生 |
| 英文摘要 | The first catalytic trifluoromethoxylation of unactivated alkenes has been developed, in which Pd(CH3CN)(2)Cl-2 was used as catalyst, AgOCF3 as trifluoromethoxide source, and Selectfluor-BF4 as oxidant. A variety of 3-OCF3 substituted piperidines were selectively obtained in good yields. Direct evidence was provided to address the facile reductive elimination of Pe(IV)-OCF3 complex to form sp(3) C-OCF3 bond. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/jacs.5b10971 |
| 语种 | 英语 |
| WOS记录号 | WOS:000367562800014 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39681]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | CHEN CHAOHUANG,Chen PH,Liu GS. Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes[J]. J. Am. Chem. Soc.,2015,137(50):15648-15651. |
| APA | CHEN CHAOHUANG,陈品红,&刘国生.(2015).Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes.J. Am. Chem. Soc.,137(50),15648-15651. |
| MLA | CHEN CHAOHUANG,et al."Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes".J. Am. Chem. Soc. 137.50(2015):15648-15651. |
入库方式： OAI收割
来源：上海有机化学研究所
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