Hypervalent Iodine Reagents Enable Chemoselective Deboronative/Decarboxylative Alkenylation by Photoredox Catalysis
文献类型：期刊论文
| 作者 | Huang HC(黄汉初); Jia KF(贾坤方); Chen YY(陈以昀) |
| 刊名 | Angew. Chem.-Int. Edit.
 |
| 出版日期 | 2015 |
| 卷号 | 54期号:6页码:1881-1884 |
| 其他题名 | 高价碘试剂通过可见光催化实现化学选择的脱硼脱羧烯基化反应 |
| 通讯作者 | 陈以昀 |
| 英文摘要 | Chemoselective C(sp3) C(sp2) coupling reactions under mild reaction conditions are useful for synthesizing alkyl-substituted alkenes having sensitive functional groups. Reported here is a visible-light-induced chemoselective alkenylation through a deboronation/decarboxylation sequence under neutral aqueous reaction conditions at room temperature. This reaction represents the first hypervalent-iodineenabled radical decarboxylative alkenylation reaction, and a novel benziodoxole-vinyl carboxylic acid reaction intermediate was isolated. This C(sp3) C(sp2) coupling reaction leads to aryl-and acyl-substituted alkenes containing various sensitive functional groups. The excellent chemoselectivity, stable reactants, and neutral aqueous reaction conditions of the reaction suggest future biomolecule applications. |
| 学科主题 | 生命有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/anie.201410176 |
| 语种 | 英语 |
| WOS记录号 | WOS:000349209200037 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39476]  |
| 专题 | 上海有机化学研究所_生命有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Huang HC,Jia KF,Chen YY. Hypervalent Iodine Reagents Enable Chemoselective Deboronative/Decarboxylative Alkenylation by Photoredox Catalysis[J]. Angew. Chem.-Int. Edit.,2015,54(6):1881-1884. |
| APA | 黄汉初,贾坤方,&陈以昀.(2015).Hypervalent Iodine Reagents Enable Chemoselective Deboronative/Decarboxylative Alkenylation by Photoredox Catalysis.Angew. Chem.-Int. Edit.,54(6),1881-1884. |
| MLA | 黄汉初,et al."Hypervalent Iodine Reagents Enable Chemoselective Deboronative/Decarboxylative Alkenylation by Photoredox Catalysis".Angew. Chem.-Int. Edit. 54.6(2015):1881-1884. |
入库方式： OAI收割
来源：上海有机化学研究所
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