Synthesis of bradyrhizose, a unique inositol-fused monosaccharide relevant to a Nod-factor independent nitrogen fixation
文献类型：期刊论文
| 作者 | Li W(李微)1; SILIPO ALBA1; MOLINARO ANTONIO1; Yu B(俞飚)1 |
| 刊名 | Chem. Commun.
 |
| 出版日期 | 2015 |
| 卷号 | 51期号:32页码:6964-6967 |
| 其他题名 | 非Nod因子依赖的固氮相关的肌醇并环单糖bradyrhizose的合成 |
| 通讯作者 | MOLINARO ANTONIO ; 俞飚 |
| 英文摘要 | The symbiosis of Bradyrhizobium sp. BTAi1 with its host plant Aeschynomene indica relies on a Nod-factor independent mechanism, wherein the Bradyrhizobium O-antigen is regarded as a key factor. This O-antigen polysaccharide is composed of a unique C10 monosaccharide, namely bradyrhizose, which has a galactose-inositol trans-fused scaffold, via a homogeneous alpha-(1 -> 7)-linkage. Herein, we report the first synthesis of bradyrhizose. The scalable synthesis requires 26 steps in a high overall yield of 9%, with the inositol scaffold being constructed effectively via a Ferrier II rearrangement from a fully functionalized C2 and C4 branched pyranose derivative. |
| 学科主题 | 生命有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/c5cc00752f |
| 语种 | 英语 |
| WOS记录号 | WOS:000352630600018 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39500]  |
| 专题 | 上海有机化学研究所_生命有机化学国家重点实验室 |
| 作者单位 | 1.中科院上海有机化学研究所, 生命有机化学国家重点实验室 2.意大利那不勒斯费德里克二世大学 |
| 推荐引用方式 GB/T 7714 | Li W,SILIPO ALBA,MOLINARO ANTONIO,et al. Synthesis of bradyrhizose, a unique inositol-fused monosaccharide relevant to a Nod-factor independent nitrogen fixation[J]. Chem. Commun.,2015,51(32):6964-6967. |
| APA | 李微,SILIPO ALBA,MOLINARO ANTONIO,&俞飚.(2015).Synthesis of bradyrhizose, a unique inositol-fused monosaccharide relevant to a Nod-factor independent nitrogen fixation.Chem. Commun.,51(32),6964-6967. |
| MLA | 李微,et al."Synthesis of bradyrhizose, a unique inositol-fused monosaccharide relevant to a Nod-factor independent nitrogen fixation".Chem. Commun. 51.32(2015):6964-6967. |
入库方式： OAI收割
来源：上海有机化学研究所
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