中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of Tricyclo[4,3,1,0(1,5)]decane Core of Plumisclerin A Using Pauson-Khand Annulation and SmI2-Mediated Radical Cyclization

文献类型:期刊论文

作者Chen JP(陈己鹏); He W(何伟); Yang ZY(杨震宇); Yao ZJ(姚祝军)
刊名Org. Lett.
出版日期2015
卷号17期号:14页码:3379-3381
其他题名Synthesis of Tricyclo[4,3,1,0(1,5)]decane Core of Plumisclerin A Using Pauson-Khand Annulation and SmI2-Mediated Radical Cyclization
通讯作者姚祝军
英文摘要An efficient synthesis of the tricyclo [4,3,1,0(1,5)]-decane core (B/C/D rings) of plumisclerin A, a unique cytotoxic marine diterpenoid, is described. A Pauson-Khand reaction and a SmI2-mediated radical 1,4-conjugate addition successfully served as key reactions for construction of the fully functionalized 5,6-fused rings and the highly strained cyclobutanol moiety with correct relative stereo chemistries, respectively.
学科主题生命有机化学
收录类别SCI
原文出处http://dx.doi.org/10.1021/acs.orglett.5b01563
语种英语
WOS记录号WOS:000358395500001
源URL[http://ir.sioc.ac.cn/handle/331003/39513]  
专题上海有机化学研究所_生命有机化学国家重点实验室
作者单位中科院上海有机化学研究所, 生命有机化学国家重点实验室
推荐引用方式
GB/T 7714
Chen JP,He W,Yang ZY,et al. Synthesis of Tricyclo[4,3,1,0(1,5)]decane Core of Plumisclerin A Using Pauson-Khand Annulation and SmI2-Mediated Radical Cyclization[J]. Org. Lett.,2015,17(14):3379-3381.
APA 陈己鹏,何伟,杨震宇,&姚祝军.(2015).Synthesis of Tricyclo[4,3,1,0(1,5)]decane Core of Plumisclerin A Using Pauson-Khand Annulation and SmI2-Mediated Radical Cyclization.Org. Lett.,17(14),3379-3381.
MLA 陈己鹏,et al."Synthesis of Tricyclo[4,3,1,0(1,5)]decane Core of Plumisclerin A Using Pauson-Khand Annulation and SmI2-Mediated Radical Cyclization".Org. Lett. 17.14(2015):3379-3381.

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来源:上海有机化学研究所

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