Synthesis of Tricyclo[4,3,1,0(1,5)]decane Core of Plumisclerin A Using Pauson-Khand Annulation and SmI2-Mediated Radical Cyclization
文献类型:期刊论文
作者 | Chen JP(陈己鹏); He W(何伟); Yang ZY(杨震宇); Yao ZJ(姚祝军) |
刊名 | Org. Lett.
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出版日期 | 2015 |
卷号 | 17期号:14页码:3379-3381 |
其他题名 | Synthesis of Tricyclo[4,3,1,0(1,5)]decane Core of Plumisclerin A Using Pauson-Khand Annulation and SmI2-Mediated Radical Cyclization |
通讯作者 | 姚祝军 |
英文摘要 | An efficient synthesis of the tricyclo [4,3,1,0(1,5)]-decane core (B/C/D rings) of plumisclerin A, a unique cytotoxic marine diterpenoid, is described. A Pauson-Khand reaction and a SmI2-mediated radical 1,4-conjugate addition successfully served as key reactions for construction of the fully functionalized 5,6-fused rings and the highly strained cyclobutanol moiety with correct relative stereo chemistries, respectively. |
学科主题 | 生命有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/acs.orglett.5b01563 |
语种 | 英语 |
WOS记录号 | WOS:000358395500001 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39513] ![]() |
专题 | 上海有机化学研究所_生命有机化学国家重点实验室 |
作者单位 | 中科院上海有机化学研究所, 生命有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Chen JP,He W,Yang ZY,et al. Synthesis of Tricyclo[4,3,1,0(1,5)]decane Core of Plumisclerin A Using Pauson-Khand Annulation and SmI2-Mediated Radical Cyclization[J]. Org. Lett.,2015,17(14):3379-3381. |
APA | 陈己鹏,何伟,杨震宇,&姚祝军.(2015).Synthesis of Tricyclo[4,3,1,0(1,5)]decane Core of Plumisclerin A Using Pauson-Khand Annulation and SmI2-Mediated Radical Cyclization.Org. Lett.,17(14),3379-3381. |
MLA | 陈己鹏,et al."Synthesis of Tricyclo[4,3,1,0(1,5)]decane Core of Plumisclerin A Using Pauson-Khand Annulation and SmI2-Mediated Radical Cyclization".Org. Lett. 17.14(2015):3379-3381. |
入库方式: OAI收割
来源:上海有机化学研究所
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