A Polystyrene-Bound Triphenylphosphine Gold(I) Catalyst for the Glycosylation of Glycosyl ortho-Hexynylbenzoates
文献类型：期刊论文
| 作者 | Zhu YG(朱玉根); LAVAL STEPHANE; Tang Y(唐宇); Lian GY(连高焱); Yu B(俞飚) |
| 刊名 | Asian J. Org. Chem.
 |
| 出版日期 | 2015 |
| 卷号 | 4期号:10页码:1034-1039 |
| 其他题名 | 聚苯乙烯固载的三苯基膦金催化剂在邻炔基苯甲酸酯给体糖苷化中的应用 |
| 通讯作者 | 俞飚 |
| 英文摘要 | The efficacy of the heterogeneous polystyrene-bound triphenylphosphine gold(I) catalyst 3 (PS-[(Ph3PAuNTf2)-N-I]; PS=polystyrene; Tf=trifluoromethanesulfonyl) in the activation of glycosyl ortho-hexynylbenzoates for glycosylation is demonstrated. The shelf-stable catalyst 3 (and its precursor 2, PS-[(Ph3PAuCl)-Cl-I]) were fully characterized by elemental analysis, X-ray photoelectron spectroscopy (XPS), energy dispersive spectroscopy (EDS), and scanning electron microscopy (SEM), and showed remarkable catalytic activities and recyclability in glycosylation reactions as well as in the skeletal rearrangement of the 1,6-enyne 4. EDS analysis demonstrated that the phosphine ligand binds the gold strongly and prevents the leaching of the metal. |
| 学科主题 | 生命有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/ajoc.201500276 |
| 语种 | 英语 |
| WOS记录号 | WOS:000362589200006 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39527]  |
| 专题 | 上海有机化学研究所_生命有机化学国家重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 生命有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhu YG,LAVAL STEPHANE,Tang Y,et al. A Polystyrene-Bound Triphenylphosphine Gold(I) Catalyst for the Glycosylation of Glycosyl ortho-Hexynylbenzoates[J]. Asian J. Org. Chem.,2015,4(10):1034-1039. |
| APA | 朱玉根,LAVAL STEPHANE,唐宇,连高焱,&俞飚.(2015).A Polystyrene-Bound Triphenylphosphine Gold(I) Catalyst for the Glycosylation of Glycosyl ortho-Hexynylbenzoates.Asian J. Org. Chem.,4(10),1034-1039. |
| MLA | 朱玉根,et al."A Polystyrene-Bound Triphenylphosphine Gold(I) Catalyst for the Glycosylation of Glycosyl ortho-Hexynylbenzoates".Asian J. Org. Chem. 4.10(2015):1034-1039. |
入库方式： OAI收割
来源：上海有机化学研究所
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