Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids
文献类型：期刊论文
| 作者 | Zhu LL(朱莉莉)1; Huang SH(黄莎华)1; Yu J(于静)1; Hong R(洪然)1 |
| 刊名 | Tetrahedron Lett.
 |
| 出版日期 | 2015 |
| 卷号 | 56期号:1页码:23-31 |
| 其他题名 | Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids |
| 通讯作者 | 朱莉莉 ; 洪然 |
| 英文摘要 | In this Digest, innovative strategies and tactics attributed to construct a full 6–6-fused bicyclo[3.2.1]octane framework of ent-kauranoids are highlighted. Although the first synthesis of ent-kaurene was reported fifty years ago, modern synthetic methods continue to sustain this field to the frontier of synthetic chemistry. Recent advances implemented new perspectives in the construction of bicycle[3.2.1]octane skeleton as well as the overall efficiency of synthesis. Biogenesis of ent-kaurene was recently revisited by comprehensive computational analysis. An updated proposal argued that ent-beyerane is derived from ent-kauranyl cation since the secondary carbocation is energetically unfavorable, which may throw light on new experimental design and further biomimicry study to better understand the origin of this vast category of ent-kauranoids. |
| 学科主题 | 天然产物有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1016/j.tetlet.2014.11.035 |
| 语种 | 英语 |
| WOS记录号 | WOS:000348259800002 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39778]  |
| 专题 | 上海有机化学研究所_中科院天然产物有机化学重点实验室 |
| 作者单位 | 1.中科院上海有机化学研究所 2.上海应用技术学院 |
| 推荐引用方式 GB/T 7714 | Zhu LL,Huang SH,Yu J,et al. Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids[J]. Tetrahedron Lett.,2015,56(1):23-31. |
| APA | 朱莉莉,黄莎华,于静,&洪然.(2015).Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids.Tetrahedron Lett.,56(1),23-31. |
| MLA | 朱莉莉,et al."Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids".Tetrahedron Lett. 56.1(2015):23-31. |
入库方式： OAI收割
来源：上海有机化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。