Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity
文献类型:期刊论文
作者 | Zhao YS(赵一爽)1; Liu Q(刘强)1; Tian P(田平)1; TAO JINGCHAO1; Lin GQ(林国强)1 |
刊名 | Org. Biomol. Chem.
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出版日期 | 2015 |
卷号 | 13期号:14页码:4174-4178 |
其他题名 | 铜催化的手性叔丁基亚磺酰胺的不对称烯丙基化: 双立体控制下的绝对非对映选择性 |
通讯作者 | 田平 ; TAO JINGCHAO |
英文摘要 | Copper-catalyzed asymmetric allylation of chiral N-tert-butane-sulfinyl imines has been described. Dual stereocontrol, through the combination of a chiral auxiliary and a chiral copper complex, has played an important role in achieving the nearly perfect diastereo-selectivities (all dr > 99 : 1), especially for ketimine substrates. |
学科主题 | 天然产物有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1039/c5ob00322a |
语种 | 英语 |
WOS记录号 | WOS:000351618000008 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39782] ![]() |
专题 | 上海有机化学研究所_中科院天然产物有机化学重点实验室 |
作者单位 | 1.郑州大学 2.中科院上海有机化学研究所, 天然产物有机合成化学重点实验室 |
推荐引用方式 GB/T 7714 | Zhao YS,Liu Q,Tian P,et al. Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity[J]. Org. Biomol. Chem.,2015,13(14):4174-4178. |
APA | 赵一爽,刘强,田平,TAO JINGCHAO,&林国强.(2015).Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity.Org. Biomol. Chem.,13(14),4174-4178. |
MLA | 赵一爽,et al."Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity".Org. Biomol. Chem. 13.14(2015):4174-4178. |
入库方式: OAI收割
来源:上海有机化学研究所
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