Tris(boratabenzene) Lanthanum Complexes: Synthesis, Structure, and Reactivity
文献类型：期刊论文
| 作者 | Wang CH(王春红); Leng XB(冷雪冰); Chen YF(陈耀峰) |
| 刊名 | Organometallics
 |
| 出版日期 | 2015 |
| 卷号 | 34期号:13页码:3216-3221 |
| 其他题名 | 三硼杂苯镧配合物: 合成、结构和反应性能 |
| 英文摘要 | A Series of tris(boratabenzerre) lanthanum complexes Were synthesized and structurally characterized. salt elimination of anhydrous LaCl3 with Li[C5H5BR] (R = H, NEt2) provided tris(boratabenzerie) lanthanum complexes [C5H5BH3](3)-LaLiCl (I) and [C(5)H(5)BNBt(2)](3)LaLiCl(THF) (2) in high yields. Hydroboration of 1-hexene or 3-hexyne with I gave the alkyl- or alkenyl-functionalized boratabenzene lanthanum complexes, [C5H5B(CH2)(5)CH3](3)LaLiCI(THF) (3) and [C5H5BC(C2H5)= CH(C2H5)](3)LaLiCl(THF) (4), in good yields. Hydroboration of N,N'-diisopropylcarbodiimide with I gave the monohydroboration product [C5H5BN(Pr-t)CHN(Pr-i)][C5H5BH](2)La (5) due to the steric bulk of the [C5H5BN(Pr-i)CHN(Pr-i)](-) ligand. Complex 5 can undergo further hydroboration with 3-hexyne or dehydrogenative coupling with phenyl acetylene to afford [C5H5BN(Pr-i)-CHN(Pr-i)][C5H5BC(C2H5)=CH(C2H5)](2)La (6) or [C5H5BN(Pr-i)CHN(Pr-i)][C5H5BC CPh)](2)La (7). |
| 学科主题 | 天然产物有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/acs.organomet.5b00262 |
| 语种 | 英语 |
| WOS记录号 | WOS:000358026500016 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39802]  |
| 专题 | 上海有机化学研究所_中科院天然产物有机化学重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Wang CH,Leng XB,Chen YF. Tris(boratabenzene) Lanthanum Complexes: Synthesis, Structure, and Reactivity[J]. Organometallics,2015,34(13):3216-3221. |
| APA | 王春红,冷雪冰,&陈耀峰.(2015).Tris(boratabenzene) Lanthanum Complexes: Synthesis, Structure, and Reactivity.Organometallics,34(13),3216-3221. |
| MLA | 王春红,et al."Tris(boratabenzene) Lanthanum Complexes: Synthesis, Structure, and Reactivity".Organometallics 34.13(2015):3216-3221. |
入库方式： OAI收割
来源：上海有机化学研究所
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