1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation
文献类型：期刊论文
| 作者 | Zheng J(郑剑); Lin JH(林锦鸿); Deng XY(邓晓云); Xiao JC(肖吉昌) |
| 刊名 | Org. Lett.
 |
| 出版日期 | 2015 |
| 卷号 | 17期号:3页码:532-535 |
| 其他题名 | DBU促进下二氟卡宾的分解及三氟甲基化 |
| 通讯作者 | 肖吉昌 |
| 英文摘要 | Difluorocarbene derived from various carbene precursors could be effectively decomposed by 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU). This decomposition process was successfully applied in the subsequent trifluoromethylation of a variety of (hetero)aryl iodides without the addition of an external fluoride ion. Mechanistic investigation revealed the detailed difluorocarbene conversion process in which the decomposed difluorocarbene is finally transformed into a fluoride ion and carbon monoxide. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ol503548s |
| 语种 | 英语 |
| WOS记录号 | WOS:000349274200036 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39703]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Zheng J,Lin JH,Deng XY,et al. 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation[J]. Org. Lett.,2015,17(3):532-535. |
| APA | 郑剑,林锦鸿,邓晓云,&肖吉昌.(2015).1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation.Org. Lett.,17(3),532-535. |
| MLA | 郑剑,et al."1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation".Org. Lett. 17.3(2015):532-535. |
入库方式： OAI收割
来源：上海有机化学研究所
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