Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species
文献类型：期刊论文
| 作者 | Zhu JM(朱杰明); Ni CF(倪传法); Gao B(高兵); Hu JB(胡金波) |
| 刊名 | J. Fluor. Chem.
 |
| 出版日期 | 2015 |
| 卷号 | 171页码:139-147 |
| 其他题名 | 单质铜调控下2-溴-1,1,2,2-四氟乙基化合物对碘苯的氟烷基化反应: R取代基对RCF2Cu物种的反应性影响研究 |
| 通讯作者 | 胡金波 |
| 英文摘要 | We have made a systematic investigation on the copper(0)-mediated tetrafluoroethylenation of iodobenzene with structurally diverse 2-bromo-1,1,2,2-tetrafluoroethyl compounds. A comparison of this reaction with 1,2,2-trifluoro-1-phenylethylation and the known functionalized difluoroalkylation demonstrates that the substituent R of alpha,alpha-difluoroalkyl copper species RCF2Cu plays a crucial role on their reactivity, which is believed to be useful for the development of new fluoroalkylation reactions under the promotion of transition metals. (C) 2014 Elsevier B.V. All rights reserved. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1016/j.jfluchem.2014.08.011 |
| 语种 | 英语 |
| WOS记录号 | WOS:000350943600022 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39713]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhu JM,Ni CF,Gao B,et al. Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species[J]. J. Fluor. Chem.,2015,171:139-147. |
| APA | 朱杰明,倪传法,高兵,&胡金波.(2015).Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species.J. Fluor. Chem.,171,139-147. |
| MLA | 朱杰明,et al."Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species".J. Fluor. Chem. 171(2015):139-147. |
入库方式： OAI收割
来源：上海有机化学研究所
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