Structure-Reactivity Relationship of Trifluoromethanesulfenates: Discovery of an Electrophilic Trifluoromethylthiolating Reagent
文献类型：期刊论文
| 作者 | Shao XX(邵欣欣); Xu CF(徐春发); Lv L(吕龙); Shen QL(沈其龙) |
| 刊名 | J. Org. Chem.
 |
| 出版日期 | 2015 |
| 卷号 | 80期号:6页码:3012-3021 |
| 其他题名 | 结构活性相关-三氟甲基次磺酸酯: 新型亲电三氟甲硫基化试剂的研制 |
| 通讯作者 | 吕龙 ; 沈其龙 |
| 英文摘要 | A family of electrophilic trifluoromethanesulfenates was prepared. Structure-reactivity relationship studies showed that the substituted groups on the aryl ring of the trifluoromethylthiolating reagent did not have an obvious influence on their reactivities. A simplified electrophilic trifluoromethylthiolating reagent 1c was then identified that can react with a wide range of nucleophiles such as Grignard reagents, arylboronic acids, alkynes, indoles, beta-ketoesters, oxindoles, and sodium sulfinates under mild reaction conditions. A variety of functional groups were tolerated under these conditions. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/jo502645m |
| 语种 | 英语 |
| WOS记录号 | WOS:000351558400006 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39716]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Shao XX,Xu CF,Lv L,et al. Structure-Reactivity Relationship of Trifluoromethanesulfenates: Discovery of an Electrophilic Trifluoromethylthiolating Reagent[J]. J. Org. Chem.,2015,80(6):3012-3021. |
| APA | 邵欣欣,徐春发,吕龙,&沈其龙.(2015).Structure-Reactivity Relationship of Trifluoromethanesulfenates: Discovery of an Electrophilic Trifluoromethylthiolating Reagent.J. Org. Chem.,80(6),3012-3021. |
| MLA | 邵欣欣,et al."Structure-Reactivity Relationship of Trifluoromethanesulfenates: Discovery of an Electrophilic Trifluoromethylthiolating Reagent".J. Org. Chem. 80.6(2015):3012-3021. |
入库方式： OAI收割
来源：上海有机化学研究所
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