Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation
文献类型：期刊论文
| 作者 | Gu Y(古阳)1; Chang DL(常大路)1; Leng XB(冷雪冰)1; Gu YC(顾玉成)1; Shen QL(沈其龙)1 |
| 刊名 | Organometallics
 |
| 出版日期 | 2015 |
| 卷号 | 34期号:12页码:3065-3071 |
| 其他题名 | Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation |
| 通讯作者 | 沈其龙 |
| 英文摘要 | The preparation of the thermally stable, well-defined NHC-ligated difluoromethylated silver complexes la,b is described. The complexes were fully characterized, and the structural assignments were ambiguously further confirmed by single-crystal X-ray diffraction. Reactions of [(SIPr)Ag(CF2H)] with a variety of activated electrophiles such as diaryliodonium salts, vinyl(aryl)iodonium salts, aryldiazonium salts, and acid chlorides in the presence or absence of CuI occurred smoothly at room temperature to generate difluoromethylated compounds in good to excellent yields. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/acs.organomet.5b00350 |
| 语种 | 英语 |
| WOS记录号 | WOS:000356903100042 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39730]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 作者单位 | 1.中科院上海有机化学研究所, 有机氟化学重点实验室 2.英国先正达 |
| 推荐引用方式 GB/T 7714 | Gu Y,Chang DL,Leng XB,et al. Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation[J]. Organometallics,2015,34(12):3065-3071. |
| APA | 古阳,常大路,冷雪冰,顾玉成,&沈其龙.(2015).Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation.Organometallics,34(12),3065-3071. |
| MLA | 古阳,et al."Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation".Organometallics 34.12(2015):3065-3071. |
入库方式： OAI收割
来源：上海有机化学研究所
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