Rhodium-Catalyzed ortho-Selective C-F Bond Borylation of Polyfluoroarenes with Bpin-Bpin
文献类型：期刊论文
| 作者 | Guo WH(郭文豪); Min QQ(闵巧桥); Gu JW(顾继伟); Zhang XG(张新刚) |
| 刊名 | Angew. Chem.-Int. Edit.
 |
| 出版日期 | 2015 |
| 卷号 | 54期号:31页码:9075-9078 |
| 其他题名 | 铑催化下多氟芳烃邻位选择性C-F键硼化 |
| 通讯作者 | 张新刚 |
| 英文摘要 | An ortho-selective CF bond borylation between N-heterocycle-substituted polyfluoroarenes and Bpin-Bpin with simple and commercially available [Rh(cod)(2)]BF4 as a catalyst is now reported. The reaction proceeds under mild reaction conditions with high efficiency and broad substrate scope, even toward monofluoroarene, thus providing a facile access to a wide range of borylated fluoroarenes that are useful for photoelectronic materials. Preliminary mechanistic studies reveal that a Rh-III/V catalytic cycle via a key intermediate rhodium(III) hydride complex [(H)(RhLn)-L-III(Bpin)] may be involved in the reaction. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/anie.201500124 |
| 语种 | 英语 |
| WOS记录号 | WOS:000358501500037 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39733]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Guo WH,Min QQ,Gu JW,et al. Rhodium-Catalyzed ortho-Selective C-F Bond Borylation of Polyfluoroarenes with Bpin-Bpin[J]. Angew. Chem.-Int. Edit.,2015,54(31):9075-9078. |
| APA | 郭文豪,闵巧桥,顾继伟,&张新刚.(2015).Rhodium-Catalyzed ortho-Selective C-F Bond Borylation of Polyfluoroarenes with Bpin-Bpin.Angew. Chem.-Int. Edit.,54(31),9075-9078. |
| MLA | 郭文豪,et al."Rhodium-Catalyzed ortho-Selective C-F Bond Borylation of Polyfluoroarenes with Bpin-Bpin".Angew. Chem.-Int. Edit. 54.31(2015):9075-9078. |
入库方式： OAI收割
来源：上海有机化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。