Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions
文献类型：期刊论文
| 作者 | Lin JH(林锦鸿); Ji YL(季云龙); Xiao JC(肖吉昌) |
| 刊名 | Curr. Org. Chem.
 |
| 出版日期 | 2015 |
| 卷号 | 19期号:16页码:1541-1553 |
| 其他题名 | 碳氢键三氟甲硫基化与三氟甲氧基化的最新进展 |
| 通讯作者 | 林锦鸿 ; 肖吉昌 |
| 英文摘要 | As both trifluoromethylthio (CF3S) and trifluoromethoxy (CF3O) moieties have proved to be valuable functionalities in pharmaceutical chemistry, trifluoromethylthiolation and trifluoromethoxylation have received a great deal of attention. For the trifluoromethylthiolation reaction, a variety of efficient methods have been developed. Among these methods, C-H trifluoromethylthiolation avoids the need to prefunctionalize substrates, meaning that this straightforward protocol is quite attractive and promising. The first section of this review summarizes recent advances in this field, including Csp(3)-H, Csp(2)-H and Csp-H trifluoromethylthiolation and the asymmetric Csp(3)-H trifluoromethylthiolation reactions. Trifluoromethoxylation with safe trifluoromethoxylation reagents remains a significant challenge. The second section of this review summarizes the recent progress in trifluoromethoxylation reaction. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.2174/1385272819666150520230727 |
| 语种 | 英语 |
| WOS记录号 | WOS:000358962300003 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39736]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Lin JH,Ji YL,Xiao JC. Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions[J]. Curr. Org. Chem.,2015,19(16):1541-1553. |
| APA | 林锦鸿,季云龙,&肖吉昌.(2015).Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions.Curr. Org. Chem.,19(16),1541-1553. |
| MLA | 林锦鸿,et al."Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions".Curr. Org. Chem. 19.16(2015):1541-1553. |
入库方式： OAI收割
来源：上海有机化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。