Copper-Promoted Trifluoromethanesulfonylation and Trifluoromethylation of Arenediazonium Tetrafluoroborates with NaSO2CF3
文献类型：期刊论文
| 作者 | Zhang K(张柯)1; Xu XH(徐修华)1; Qing FL(卿凤翎)1 |
| 刊名 | J. Org. Chem.
 |
| 出版日期 | 2015 |
| 卷号 | 80期号:15页码:7658-7665 |
| 其他题名 | 铜参与芳基重氮盐与NaSO2CF3的三氟甲磺酰化和三氟甲基化反应 |
| 通讯作者 | 徐修华 ; 卿凤翎 |
| 英文摘要 | A tunable chemoselective trifluoromethanesulfonylation and trifluoromethylation of arenediazonium tetrafluoroborates with Langlois' reagent (NaSO2CF3) was developed. The Cu2O-catalyzed reaction in DMSO gave aryl trifluoromethanesulfones as the major products. On the other hand, the trifluoromethylated arenes were produced in the presence of oxidant tert-butyl hydroperoxide, CuBF4(MeCN)(4), and 2,2';6',2 ''-terpyridine (tpy). Both of these transformations proceed under mild conditions and tolerate functional groups. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/acs.joc.5b01295 |
| 语种 | 英语 |
| WOS记录号 | WOS:000359393500037 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39739]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 作者单位 | 1.东华大学 2.中科院上海有机化学研究所, 有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhang K,Xu XH,Qing FL. Copper-Promoted Trifluoromethanesulfonylation and Trifluoromethylation of Arenediazonium Tetrafluoroborates with NaSO2CF3[J]. J. Org. Chem.,2015,80(15):7658-7665. |
| APA | 张柯,徐修华,&卿凤翎.(2015).Copper-Promoted Trifluoromethanesulfonylation and Trifluoromethylation of Arenediazonium Tetrafluoroborates with NaSO2CF3.J. Org. Chem.,80(15),7658-7665. |
| MLA | 张柯,et al."Copper-Promoted Trifluoromethanesulfonylation and Trifluoromethylation of Arenediazonium Tetrafluoroborates with NaSO2CF3".J. Org. Chem. 80.15(2015):7658-7665. |
入库方式： OAI收割
来源：上海有机化学研究所
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