Diphenyliodonium-Catalyzed Fluorination of Arynes: Synthesis of ortho-Fluoroiodoarenes
文献类型：期刊论文
| 作者 | Ceng YW(曾裕文); Li GY(李光玉); Hu JB(胡金波) |
| 刊名 | Angew. Chem.-Int. Edit.
 |
| 出版日期 | 2015 |
| 卷号 | 54期号:37页码:10773-10777 |
| 其他题名 | 以双芳基碘(III)盐催化的芳炔氟化来合成邻氟代碘代芳烃 |
| 通讯作者 | 胡金波 |
| 英文摘要 | Described is a one-pot vicinal fluorination-iodination of arynes at room temperature. The diphenyliodonium salt proved to be a privileged catalyst for this nucleophilic fluorination process using CsF as a fluorine source, and a subsequent facile electrophilic iodination with C4F9I was also found to be crucial to ensure the efficient fluorination. This new synthetic protocol has a broad substrate scope under mild reaction conditions. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/anie.201503308 |
| 语种 | 英语 |
| WOS记录号 | WOS:000360628500009 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39743]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Ceng YW,Li GY,Hu JB. Diphenyliodonium-Catalyzed Fluorination of Arynes: Synthesis of ortho-Fluoroiodoarenes[J]. Angew. Chem.-Int. Edit.,2015,54(37):10773-10777. |
| APA | 曾裕文,李光玉,&胡金波.(2015).Diphenyliodonium-Catalyzed Fluorination of Arynes: Synthesis of ortho-Fluoroiodoarenes.Angew. Chem.-Int. Edit.,54(37),10773-10777. |
| MLA | 曾裕文,et al."Diphenyliodonium-Catalyzed Fluorination of Arynes: Synthesis of ortho-Fluoroiodoarenes".Angew. Chem.-Int. Edit. 54.37(2015):10773-10777. |
入库方式： OAI收割
来源：上海有机化学研究所
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