Palladium-Catalyzed Difluoroalkylation of Isocyanides: Access to Difluoroalkylated Phenanthridine Derivatives
文献类型：期刊论文
| 作者 | Gu JW(顾继伟); Zhang XG(张新刚) |
| 刊名 | Org. Lett.
 |
| 出版日期 | 2015 |
| 卷号 | 17期号:21页码:5384-5387 |
| 其他题名 | 钯催化下异氰的二氟烷基化 |
| 通讯作者 | 张新刚 |
| 英文摘要 | An efficient and general method for the synthesis of difluoroalkylated phenanthridine derivatives through palladium-catalyzed reaction of difluoroalkyl bromides with isocyanides is described. The reaction can also be extended to perfluoroalkyl iodides. Mechanistic studies reveal that a difluoroalkyl radical via a single-electron-transfer pathway is involved in the reaction. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/acs.orglett.5b02739 |
| 语种 | 英语 |
| WOS记录号 | WOS:000364434900060 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39753]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Gu JW,Zhang XG. Palladium-Catalyzed Difluoroalkylation of Isocyanides: Access to Difluoroalkylated Phenanthridine Derivatives[J]. Org. Lett.,2015,17(21):5384-5387. |
| APA | 顾继伟,&张新刚.(2015).Palladium-Catalyzed Difluoroalkylation of Isocyanides: Access to Difluoroalkylated Phenanthridine Derivatives.Org. Lett.,17(21),5384-5387. |
| MLA | 顾继伟,et al."Palladium-Catalyzed Difluoroalkylation of Isocyanides: Access to Difluoroalkylated Phenanthridine Derivatives".Org. Lett. 17.21(2015):5384-5387. |
入库方式： OAI收割
来源：上海有机化学研究所
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