Chemically oxidative fluorination with fluoride ions
文献类型：期刊论文
| 作者 | Ni CF(倪传法); Jiang FZ(姜範洲); Ceng YW(曾裕文); Hu JB(胡金波) |
| 刊名 | J. Fluor. Chem.
 |
| 出版日期 | 2015 |
| 卷号 | 179页码:3-13 |
| 其他题名 | 以氟负离子进行的化学氧化氟化 |
| 通讯作者 | 胡金波 |
| 英文摘要 | Although the chemical oxidation of fluoride ions is generally challenging due to the high electronegativity of fluorine, in the past four years, a number of oxidative fluorination reactions via the reactivity umpolung of substrates or fluorides have been developed. These reactions can introduce fluorine into nucleophilic or electron-neutral systems. This short review provides a summary on the recent developments of oxidative fluorination of arenes, alkanes, and alkenes with fluorides promoted by various oxidants. These newly developed reactions are of high selectivity and efficiency, and provide a pathway for the more efficient use of the abundant, yet less nucleophilic fluorides. (C) 2015 Elsevier B.V. All rights reserved. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1016/j.jfluchem.2015.06.026 |
| 语种 | 英语 |
| WOS记录号 | WOS:000364881000002 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39760]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Ni CF,Jiang FZ,Ceng YW,et al. Chemically oxidative fluorination with fluoride ions[J]. J. Fluor. Chem.,2015,179:3-13. |
| APA | 倪传法,姜範洲,曾裕文,&胡金波.(2015).Chemically oxidative fluorination with fluoride ions.J. Fluor. Chem.,179,3-13. |
| MLA | 倪传法,et al."Chemically oxidative fluorination with fluoride ions".J. Fluor. Chem. 179(2015):3-13. |
入库方式： OAI收割
来源：上海有机化学研究所
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