Visible-Light-Induced Photocatalysis of 1,1,1-Trifluoro-2-iodoethane with Alkylalkenes and Silyl Enol Ethers
文献类型：期刊论文
| 作者 | Huang MW(黄美薇)1; Li L(李伦)1; Zhao ZG(赵志刚)1; Chen QY(陈庆云)1; Guo Y(郭勇)1 |
| 刊名 | Synthesis
 |
| 出版日期 | 2015 |
| 卷号 | 47期号:24页码:3891-3900 |
| 其他题名 | 可见光促进的烯烃和烯醇硅醚与三氟碘乙烷的三氟乙基化反应 |
| 通讯作者 | 赵志刚 ; 陈庆云 ; 郭勇 |
| 英文摘要 | Reactions of 1,1,1-trifluoro-2-iodoethane with alkylalkenes and silyl enol ethers were performed in the presence of a catalytic amount of fac-Ir(ppy)(3) and an excessive amount of Hunig's base in acetonitrile irradiated by a 24 W fluorescent lamp under nitrogen atmosphere for 48 hours. The visible-light-induced photoredox reactions introduce simultaneously a 2,2,2-trifluoroethyl group and an iodine atom to both sides of the double bond of ordinary alkenes via an atom-transfer radical addition (ATRA). The same reaction with silyl enol ethers generates -trifluoromethyl ketones, which are typically a challenge to synthesize. The reactions proved to be tolerant of a variety of functionalities. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1055/s-0035-1560260 |
| 语种 | 英语 |
| WOS记录号 | WOS:000366209800008 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39765]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 作者单位 | 1.西南民族大学 2.中科院上海有机化学研究所, 有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Huang MW,Li L,Zhao ZG,et al. Visible-Light-Induced Photocatalysis of 1,1,1-Trifluoro-2-iodoethane with Alkylalkenes and Silyl Enol Ethers[J]. Synthesis,2015,47(24):3891-3900. |
| APA | 黄美薇,李伦,赵志刚,陈庆云,&郭勇.(2015).Visible-Light-Induced Photocatalysis of 1,1,1-Trifluoro-2-iodoethane with Alkylalkenes and Silyl Enol Ethers.Synthesis,47(24),3891-3900. |
| MLA | 黄美薇,et al."Visible-Light-Induced Photocatalysis of 1,1,1-Trifluoro-2-iodoethane with Alkylalkenes and Silyl Enol Ethers".Synthesis 47.24(2015):3891-3900. |
入库方式： OAI收割
来源：上海有机化学研究所
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