Microwave-assisted synthesis of dialkylphosphinic acids and a structure-reactivity study in rare earth metal extraction
文献类型：期刊论文
| 作者 | Du RB(杜若冰); An HY(安华英); Zhang SH(张素辉); Yu DH(余东海); Xiao JC(肖吉昌) |
| 刊名 | RSC Adv.
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:126页码:104258-104262 |
| 其他题名 | 微波促进下双烷基次膦酸的合成及在稀土萃取中的构效关系研究 |
| 通讯作者 | 肖吉昌 |
| 英文摘要 | Dialkylphosphinic acids were synthesised by a microwave-assisted method with high yields and wide substrate applicability. A structure-reactivity study indicates that an increase in steric hindrance in the beta position led to a decrease of extraction ratio and heavy rare earth element separation activity. A computational study was also conducted to understand the steric effect. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/c5ra23483b |
| 语种 | 英语 |
| WOS记录号 | WOS:000366433700060 |
| 源URL | [http://ir.sioc.ac.cn/handle/331003/39768]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 作者单位 | 中科院上海有机化学研究所, 有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Du RB,An HY,Zhang SH,et al. Microwave-assisted synthesis of dialkylphosphinic acids and a structure-reactivity study in rare earth metal extraction[J]. RSC Adv.,2015,5(126):104258-104262. |
| APA | 杜若冰,安华英,张素辉,余东海,&肖吉昌.(2015).Microwave-assisted synthesis of dialkylphosphinic acids and a structure-reactivity study in rare earth metal extraction.RSC Adv.,5(126),104258-104262. |
| MLA | 杜若冰,et al."Microwave-assisted synthesis of dialkylphosphinic acids and a structure-reactivity study in rare earth metal extraction".RSC Adv. 5.126(2015):104258-104262. |
入库方式： OAI收割
来源：上海有机化学研究所
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