Cross-Coupling between Difluorocarbene and Carbene-Derived Intermediates Generated from Diazocompounds for the Synthesis of gem-Difluoroolefins
文献类型:期刊论文
作者 | Zheng J(郑剑)1; Lin JH(林锦鸿)1; Yu LY(余柳英)1; Wei Y(魏云)1; Zheng X(郑兴)1; Xiao JC(肖吉昌)1 |
刊名 | Org. Lett. |
出版日期 | 2015 |
卷号 | 17期号:24页码:6150-6153 |
其他题名 | 二氟卡宾与重氮卡宾的交叉偶联 |
通讯作者 | 肖吉昌 |
英文摘要 | Cross-coupling between difluorocarbene and carbene-derived intermediates generated from diazocompounds was developed to give gem-difluoroolefins, which constitutes a fast practical pathway to achieve hindered gem-difluoroolefins. The cross-coupling between difluorocarbene and aryl diazoacetates proceeded smoothly in the presence of a copper source, whereas its coupling with diaryl diazomethanes occurred well under metal-free conditions. A mechanism involving a copperdifluorocarbene complex was proposed |
学科主题 | 氟化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/acs.orglett.5b03159 |
语种 | 英语 |
WOS记录号 | WOS:000366878300054 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39769] |
专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
作者单位 | 1.中科院上海有机化学研究所, 有机氟化学重点实验室 2.南华大学 |
推荐引用方式 GB/T 7714 | Zheng J,Lin JH,Yu LY,et al. Cross-Coupling between Difluorocarbene and Carbene-Derived Intermediates Generated from Diazocompounds for the Synthesis of gem-Difluoroolefins[J]. Org. Lett.,2015,17(24):6150-6153. |
APA | 郑剑,林锦鸿,余柳英,魏云,郑兴,&肖吉昌.(2015).Cross-Coupling between Difluorocarbene and Carbene-Derived Intermediates Generated from Diazocompounds for the Synthesis of gem-Difluoroolefins.Org. Lett.,17(24),6150-6153. |
MLA | 郑剑,et al."Cross-Coupling between Difluorocarbene and Carbene-Derived Intermediates Generated from Diazocompounds for the Synthesis of gem-Difluoroolefins".Org. Lett. 17.24(2015):6150-6153. |
入库方式: OAI收割
来源:上海有机化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。