中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Cross-Coupling between Difluorocarbene and Carbene-Derived Intermediates Generated from Diazocompounds for the Synthesis of gem-Difluoroolefins

文献类型:期刊论文

作者Zheng J(郑剑)1; Lin JH(林锦鸿)1; Yu LY(余柳英)1; Wei Y(魏云)1; Zheng X(郑兴)1; Xiao JC(肖吉昌)1
刊名Org. Lett.
出版日期2015
卷号17期号:24页码:6150-6153
其他题名二氟卡宾与重氮卡宾的交叉偶联
通讯作者肖吉昌
英文摘要Cross-coupling between difluorocarbene and carbene-derived intermediates generated from diazocompounds was developed to give gem-difluoroolefins, which constitutes a fast practical pathway to achieve hindered gem-difluoroolefins. The cross-coupling between difluorocarbene and aryl diazoacetates proceeded smoothly in the presence of a copper source, whereas its coupling with diaryl diazomethanes occurred well under metal-free conditions. A mechanism involving a copperdifluorocarbene complex was proposed
学科主题氟化学
收录类别SCI
原文出处http://dx.doi.org/10.1021/acs.orglett.5b03159
语种英语
WOS记录号WOS:000366878300054
源URL[http://ir.sioc.ac.cn/handle/331003/39769]  
专题上海有机化学研究所_中科院有机氟化学重点实验室
作者单位1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.南华大学
推荐引用方式
GB/T 7714
Zheng J,Lin JH,Yu LY,et al. Cross-Coupling between Difluorocarbene and Carbene-Derived Intermediates Generated from Diazocompounds for the Synthesis of gem-Difluoroolefins[J]. Org. Lett.,2015,17(24):6150-6153.
APA 郑剑,林锦鸿,余柳英,魏云,郑兴,&肖吉昌.(2015).Cross-Coupling between Difluorocarbene and Carbene-Derived Intermediates Generated from Diazocompounds for the Synthesis of gem-Difluoroolefins.Org. Lett.,17(24),6150-6153.
MLA 郑剑,et al."Cross-Coupling between Difluorocarbene and Carbene-Derived Intermediates Generated from Diazocompounds for the Synthesis of gem-Difluoroolefins".Org. Lett. 17.24(2015):6150-6153.

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来源:上海有机化学研究所

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