Ordered Mesoporous Polymers for Biomass Conversions and Cross-Coupling Reactions
文献类型：期刊论文
| 作者 | Liu, Fujian1,2; Wu, Qin1; Liu, Chen1; Qi, Chenze1; Huang, Kuan2; Zheng, Anmin4; Dai, Sheng2,3 |
| 刊名 | CHEMSUSCHEM
 |
| 出版日期 | 2016-09-08 |
| 卷号 | 9期号:17页码:2496-2504 |
| 关键词 | biomass conversions heterogeneous catalysis ordered mesoporous polymers reusability solvent free |
| 英文摘要 | Amino group-functionalized, ordered mesoporous polymers (OMP-NH2) were prepared using a solvent-free synthesis by grinding mixtures of solid raw precursors (aminophenol, terephthaldehyde), using block copolymer templates, and curing at 140-180 degrees C. OMP-NH2 was functionalized with acidic sites and incorporated with palladium, giving multifunctional solid catalysts with large Brunauer-Emmett-Teller (BET) surface areas, abundant and ordered mesopores, good thermal stabilities, controllable concentrations, and good dispersion of active centers. The resultant solid catalysts showed excellent catalytic activities and good reusability in biomass conversions and cross-coupling reactionsmuch superior to those of various reported solid catalysts such as Amberlyst 15, SBA-15-SO3H, and Pd/C and comparable to those of homogeneous catalysts such as heteropoly acid, HCl, and palladium acetate. A facile green approach was developed for the synthesis of ordered mesoporous polymeric solid catalysts with excellent activities for conversion of low-cost feedstocks into useful chemicals and clean biofuels. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | COVALENT ORGANIC FRAMEWORKS ; SOLID ACID CATALYSTS ; IONIC LIQUIDS ; CARBON FRAMEWORKS ; PORE-SIZE ; CELLULOSE ; TEMPLATES ; FUNCTIONALIZATION ; DEPOLYMERIZATION ; TRANSFORMATION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000383679600031 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/9610]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Shaoxing Univ, Coll Chem & Chem Engn, Shaoxing 312000, Peoples R China 2.Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA 3.Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA 4.Wuhan Inst Phys & Math, Wuhan Ctr Magnet Resonance, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Fujian,Wu, Qin,Liu, Chen,et al. Ordered Mesoporous Polymers for Biomass Conversions and Cross-Coupling Reactions[J]. CHEMSUSCHEM,2016,9(17):2496-2504. |
| APA | Liu, Fujian.,Wu, Qin.,Liu, Chen.,Qi, Chenze.,Huang, Kuan.,...&Dai, Sheng.(2016).Ordered Mesoporous Polymers for Biomass Conversions and Cross-Coupling Reactions.CHEMSUSCHEM,9(17),2496-2504. |
| MLA | Liu, Fujian,et al."Ordered Mesoporous Polymers for Biomass Conversions and Cross-Coupling Reactions".CHEMSUSCHEM 9.17(2016):2496-2504. |
入库方式： OAI收割
来源：武汉物理与数学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。