Codoping Strategy To Improve Stability and Permeability of Ba0.6Sr0.4FeO3-delta-Based Perovskite Membranes
文献类型：期刊论文
| 作者 | He, Guanghu1 ; Cao, Zhengwen2,4; Liang, Wenyuan1; Zhang, Yan1; Liu, Xin3; Caro, Juergen2; Jiang, Heqing1
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| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
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| 出版日期 | 2016-10-05 |
| 卷号 | 55期号:39页码:10386-10393 |
| 英文摘要 | To improve the stability and oxygen permeability of Ba0.6Sr0.4FeO3-delta (BSF)-based perovskite membranes, an Mg and Zr codoping strategy is proposed. The characterization by X-ray diffraction, Mossbauer spectroscopy and oxygen permeation measurements revealed that single-element Mg doping could improve the oxygen permeability of BSF-based membranes. However, in situ XRD measurements indicated that the single-element Mg doping exhibits a poor thermal stability at low oxygen partial pressure. Single-element Zr doping could improve the structure stability of BSF-based perovskites but lead to a serious decrease of oxygen permeability. Compared with the BSF-based perovskites doped by either Mg or Zr alone, Mg and Zr codoped perovskite Ba0.6Sr0.4Fe0.8Mg0.15Zr0.05O3-delta showed a better stability than single-element Mg doping and exhibited a higher oxygen permeability than single-element Zr doping. For the Mg and Zr codoped BSF, the oxygen permeation flux reached 0.78 mL min(-1) cm(-2) at 950 degrees C under an air/He oxygen partial pressure gradient. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | OXYGEN PERMEATION PROPERTIES ; HYDROGEN-PRODUCTION ; MIXED CONDUCTIVITY ; CERAMIC MEMBRANES ; MOSSBAUER-SPECTRA ; SEPARATION ; OXIDE ; REACTOR ; CONVERSION ; METHANE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000384952300018 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/9080]  |
| 专题 | 青岛生物能源与过程研究所_膜分离与催化团队 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Leibniz Univ Hannover, Inst Phys Chem & Electrochem, Callinstr 3-3A, D-30167 Hannover, Germany 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 4.Max Planck Inst Kohlenforsch, Kaiser Wilhelm Pl 1, D-45470 Mulheim, Germany |
| 推荐引用方式 GB/T 7714 | He, Guanghu,Cao, Zhengwen,Liang, Wenyuan,et al. Codoping Strategy To Improve Stability and Permeability of Ba0.6Sr0.4FeO3-delta-Based Perovskite Membranes[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2016,55(39):10386-10393. |
| APA | He, Guanghu.,Cao, Zhengwen.,Liang, Wenyuan.,Zhang, Yan.,Liu, Xin.,...&Jiang, Heqing.(2016).Codoping Strategy To Improve Stability and Permeability of Ba0.6Sr0.4FeO3-delta-Based Perovskite Membranes.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,55(39),10386-10393. |
| MLA | He, Guanghu,et al."Codoping Strategy To Improve Stability and Permeability of Ba0.6Sr0.4FeO3-delta-Based Perovskite Membranes".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 55.39(2016):10386-10393. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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