Crystal structure, tunable emission and applications of Ca1-xAl1-xSi1+xN3-xOx :RE (x=0-0.22, RE = Ce3+, Eu2+) solid solution phosphors for white light-emitting diodes
文献类型:期刊论文
作者 | Li, Shuxing1,2,3; Wang, Le4; Zhu, Qiangqiang5; Tang, Daiming6; Liu, Xuejian1; Cheng, Guofeng7; Lu, Lu8; Takeda, Takashi2; Hirosaki, Naoto2; Huang, Zhengren1 |
刊名 | JOURNAL OF MATERIALS CHEMISTRY C |
出版日期 | 2016-12-21 |
卷号 | 4期号:47页码:11219-11230 |
英文摘要 | CaAlSiN3:Eu2+ is a very promising red phosphor for high color rendering white light-emitting diodes (wLEDs), but a large part of its emission covers wavelengths longer than 700 nm, which is not detectable by the human eye and thus wasted. Optimizing its luminescence properties will allow us to further enhance the overall optical properties of wLEDs. In this contribution, the luminescence spectra of Ce3+ or Eu2+-activated CaAlSiN3 were tuned and tailored by introducing isostructural Si2N2O to form solid solutions of Ca1-xAl1-xSi1+xN3-xOx (x = 0-0.22). The structural evolutions, microstructure, luminescence, thermal quenching and quantum efficiency of Ca1-xAl1-xSi1+xN3-xOx:RE (RE = Ce3+, Eu2+) were investigated and clarified by using various analytic techniques. Upon introducing Si2N2O into CaAISiN(3), the Ce3+-doped Ca1-xAl1-xSi1+xN3-xOx shifted its peak emission from 606 to 575 nm and retained the band width of 145 nm, whereas the Eu2+-doped one blue-shifted its emission from 650 to 638 nm and broadened its band width from 90 to 122 nm, owing to the structural distortion and disorder as well as the band gap broadening associated with the solid solution formation. By combining these phosphors with a blue LED, high color rendering (Ra) and luminous efficacy (eta) white LEDs were realized (Ra = 82.5 and eta = 104 lm W-1 for the Ce3+-doped phosphors, and Ra = 97 and eta = 101 lm W-1 for the Eu2+-doped phosphors). |
WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
类目[WOS] | Materials Science, Multidisciplinary ; Physics, Applied |
研究领域[WOS] | Materials Science ; Physics |
关键词[WOS] | PARTICLE-DIAGNOSIS APPROACH ; EU2+-DOPED LUMINESCENT MATERIALS ; OPTICAL-PROPERTIES ; COMBINATORIAL APPROACH ; OXYNITRIDE PHOSPHORS ; CATION SUBSTITUTION ; ALPHA-SIALON ; HOST LATTICE ; PHOTOLUMINESCENCE ; LEDS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000390725800027 |
源URL | [http://ir.sic.ac.cn/handle/331005/21924] |
专题 | 上海硅酸盐研究所_结构陶瓷与复合材料工程研究中心_期刊论文 |
作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China 2.Natl Inst Mat Sci, Sialon Grp, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.China Jiliang Univ, Coll Opt & Elect Technol, Hangzhou 310018, Zhejiang, Peoples R China 5.Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Key Lab Mat High Power Laser, Shanghai 201800, Peoples R China 6.Natl Inst Mat Sci, Thermal Energy Mat Grp, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan 7.Chinese Acad Sci, Shanghai Inst Ceram, Anal & Testing Ctr Inorgan Mat, Shanghai 200050, Peoples R China 8.Beijing Yuji Xinguang Optoelect Technol Co Ltd, Beijing 101111, Peoples R China 9.Xiamen Univ, Coll Mat, Xiamen 361005, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Shuxing,Wang, Le,Zhu, Qiangqiang,et al. Crystal structure, tunable emission and applications of Ca1-xAl1-xSi1+xN3-xOx :RE (x=0-0.22, RE = Ce3+, Eu2+) solid solution phosphors for white light-emitting diodes[J]. JOURNAL OF MATERIALS CHEMISTRY C,2016,4(47):11219-11230. |
APA | Li, Shuxing.,Wang, Le.,Zhu, Qiangqiang.,Tang, Daiming.,Liu, Xuejian.,...&Xie, Rong-Jun.(2016).Crystal structure, tunable emission and applications of Ca1-xAl1-xSi1+xN3-xOx :RE (x=0-0.22, RE = Ce3+, Eu2+) solid solution phosphors for white light-emitting diodes.JOURNAL OF MATERIALS CHEMISTRY C,4(47),11219-11230. |
MLA | Li, Shuxing,et al."Crystal structure, tunable emission and applications of Ca1-xAl1-xSi1+xN3-xOx :RE (x=0-0.22, RE = Ce3+, Eu2+) solid solution phosphors for white light-emitting diodes".JOURNAL OF MATERIALS CHEMISTRY C 4.47(2016):11219-11230. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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